CONTENTS of journal "OIL & GAS CHEMISTRY" 2·2019 (Russia)
DEVELOPMENT STRATEGY
THE PROSPECTS FOR THE DEVELOPMENT OF OIL AND GASCHEMISTRY IN RUSSIA. PROJECTED OIL AND GAS CHEMICAL COMPLEXES AND THOSE UNDER CONSTRUCTION (P. 5-12)
Irina A. Golubeva, Denis S. Khudyakov, Elena V. Rodina
Gubkin Russian State University of Oil and Gas (National Research University), 119991, Moscow, Russia
ORCID: 0000-0002-4879-1214, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0002-4617-8643, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0001-9082-3067, E-mail: rodina Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
Analysis of the state and the prospects for the development of the oil and gas chemical industry in Russia is carried out. Problems for the development of the Russian oil and gas chemical industry, first of all a shortage of pyrolysis capacities to produce different monomers are considered. It is shown that hi-tech oil and gas chemical capacities make it possible to obtain products with high added value and to increase exponentially export income of such countries as Russia having rich reserves of hydrocarbon raw materials. The state and the prospects for realization of the main projected oil and gas chemical complexes and those under construction in Russia are considered. The prospects of the development of cluster approach to formation of the centers for deep processing of hydrocarbons with a production kernel in the form of large-scale pyrolysis capacities and with the subsequent production of plastic, rubbers and products of organic synthesis and also their processing in final products for the consumer market are shown.
KEYWORDS: oil and gaschemistry, complex, project, technologies, cluster model, high added value, polymers, plastic, rubbers.
For citation: Golubeva I.A., Khudyakov D.S., Rodina E.V. THE PROSPECTS FOR THE DEVELOPMENT OF OIL AND GASCHEMISTRY IN RUSSIA. PROJECTED OIL AND GAS CHEMICAL COMPLEXES AND THOSE UNDER CONSTRUCTION. Oil & Gas Chemistry. 2019, no. 2, pp. 5–12.
DOI:10.24411/2310-8266-2019-10201
CHEMICAL TECHNOLOGIES AND PRODUCTS
APPLICATION OF MICROWAVE IRRADIATION ON EXTRA-HEAVY CRUDE OIL (P. 13-17)
Alexander YU. Leontyev1, Olga YU. Poletaeva1,
Elbey R. Babaev2, Pervin SH. Mamedova2
1Ufa State Petroleum Technological University, 450062, Ufa, Russia
ORCID: http://orcid.org/0000-0003-3363-6841, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: http://orcid.org/0000-0002-9602-0051, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
2Institute of Chemistry of Additives after Academician A.M. Guliyev, Azerbaidjan National Academy of Sciences, AZ1029, Baku, Azerbaidjan Republic
ORCID: https://orcid.org/0000-0001-7614-4797, Е-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: https://orcid.org/0000-0001-6711-6823, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
In this research, the effects of direct heating and ultrahigh frequency electromagnetic field on extra-heavy crude oilwere investigated. There were considered all the advantages of microwave radiation compared with direct heating. The effect of direct heating and microwave irradiation on rheological properties of extra-heavy crude oil has been experimentally investigated. Oils from the Volga-Ural oil and gas-bearing basin and Yarega field with a density of over 910 kg/m3 were used as test item. There were carried out a series of experiments in which were studied changes of viscosity from the duration and power of microwave irradiation. During the study the oil flow curves were taken under direct heating with a step of 10 °C. The dependence of the dynamic viscosity from the temperature was constructed. The flow curves after the microwave irradiationwere also taken. Oil viscosity change during storage after direct heating and microwave irradiation was also shown. Microwave has an ambiguous effect on the rheological properties of oils of different composition. According to the results obtained, it can be assumed that after microwave irradiation, a change occurs in the oil dispersion system, which can not only improve the rheological properties but also worsen them.
KEYWORDS: extra heavy crude oil, direct heating, microwave irradiation, oil disperse system, flow curves, rheological properties, disperse system.
For citation: Leontyev A.YU., Poletaeva O.YU., Babaev E.R., Mamedova P.SH. APPLICATION OF MICROWAVE IRRADIATION ON EXTRA-HEAVY CRUDE OIL. Oil & Gas Cheуmistry. 2019, no. 2, pp. 13–17.
DOI:10.24411/2310-8266-2019-10202
Acknowledgments: The reported study was funded by RFBR ac- cording to the research project No 18-55-06018. This work was supported by the Science Devel- opment Foundation under the President of the Repub- lic of Azerbaijan-Grant No EIF-BGM-4-RFTF-1/2017- 21/12/4.
SYNTHESIS OF RENIUM COMPLEXES AND THE FEATURES OF THE COORDINATION OF NICOTINIC ACID (P. 18-20)
Minira M. Agaguseynova, Fidan D. Gudratova
Azerbaijan State University of Oil and Industry, AZ1010, Baku, Azerbaidjan Republic
ORCID: https://orcid.org/0000-0003-1899-3998, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The reaction of complexformation of nitrosopentachlororenate ammonium with nicotine acid in different conditions were investigated. The composition and structure of the received complexes have been studied by the methods of thermogravimetry, IR-spectroscopy and element analysis. It has been shown together with monodentate coordination of ligand through nitrogen molecular of heterocycle in various complexes bidentate coordination exists too.
KEYWORDS: rhenium, nicotine acid, complex, IR spectroscopy, thermogravimetric analysis.
For citation: Golubeva I.A., Khudyakov D.S., Rodina E.V. THE PROSPECTS FOR THE DEVELOPMENAgaguseynova M.M., Gudratova F.D. SYNTHESIS OF RENIUM COMPLEXES AND THE FEATURES OF THE COORDINATION OF NICOTINIC ACID. Oil & Gas Cheуmistry. 2019, no. 2, pp. 18–20.
DOI:10.24411/2310-8266-2019-10203
INFLUENCE OF ZEOLITE REGENERATION GAS OF DRYING PROCESS ON THE QUALITY OF COMMERCIAL GAS OF ASTRAKHAN GAS PROCESSING PLANT DURING HIGH AMBIENT TEMPERATURES (P. 21-24)
Oleg V. Tanayants, Viktor V. Shardyko, Olga N. Karatun, Sergey V. Drachevskiy
Astrakhan Gas Processing Plant, 414000, Astrakhan, Russia
ORCID: 0000-0003-0703-8880, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0003-3175-8722, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0002-5580-5813, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0003-4311-8220, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
A study was made of the effect of the regeneration gas of zeolites from the drying process of the Astrakhan gas processing plant on the quality of gas produced according to the Gazprom 089-2010 STO «Natural combustible gas, supplied and transported via main gas pipelines. Technical conditions» and prospects for commercial gas production according to the requirements of TR EAEC 046/2018. The assessment of the effect of zeolite regeneration gas is presented. The adsorbent content of sulfur compounds in products (commercial gas) during high ambient temperatures is given.
KEYWORDS: desiccated gas drying, regeneration gas, zeolites, adsorption, sulfur compounds, commercial gas generation, fixed mileage, high ambient temperature.
For citation: Tanayants O.V., Shardyko V.V., Karatun O.N., Drachevskiy S.V. THE EFFECT OF GAS OF REGENERATION OF OSUSHKIN'S ZEOLITES QUALITY OF COMMERCIAL GAS OF ASTRAKHAN GPP IN THE PERIOD OF HIGH AMBIENT AIR TEMPERATURES. Oil & Gas Cheуmistry. 2019, no. 2, pp. 21–24.
DOI:10.24411/2310-8266-2019-10204
DIFFICULT CONDITIONS BEHAVIOR OF HIGHLY POLAR POLYGLYCOL COMPRESSOR LUBRICANTS (P. 25-29)
Kirill A. Ovchinnikov1, Jylia A. Malinovskaya1, Andrey A. Pimenov1,
Julia A. Zhuravleva1, Ida A. Kulikova2, Vladimir A. Tyschenko2,
Sergey A. Filipchenko3
1Samara State Technical University, 443100, Samara, Russia
ORCID: 0000-0002-9298-3475, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0003-4880-7041, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0002-2032-573Х, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0001-7311-3936, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
2Midvolga Research Refinery Institute , 446200, Novokuybyshevsk, Russia
ORCID: 0000-0002-7172-2559, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
3Renforce-NT, 443031, Samara, Russia
E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The article provides information on the operation of the compressor in the oilfield, pumping associated petroleum gas with a high water content. Deposits formed in compressor oil were analyzed, and the stability of fresh and aged oil with different water contents was studied.
KEYWORDS: compressor oil, micelles, deposits, associated petroleum gas.
For citation: Ovchinnikov K.A., Malinovskaya YU.A., Pimenov A.A., Zhuravleva YU.A., Kulikova I.A., Tyschenko V.A., Filipchenko S.A. DIFFICULT CONDITIONS BEHAVIOR OF HIGHLY POLAR POLYGLYCOL COMPRESSOR LUBRICANTS. Oil & Gas Cheуmistry. 2019, no. 2, pp. 25–29.
DOI:10.24411/2310-8266-2019-10205
COMPARATIVE ANALYSIS OF ASSOCIATED PETROLEUM GAS UTILIZATION TECHNOLOGIES AT THE FACILITIES OF ROSNEFT OIL COMPANY (P. 30-35)
Evgeniy T. Klimenko., Vadim O. Rostovtsev., Anastasiya E. Solodilova
Gubkin Russian State University of Oil and Gas (National Research University), 119991, Moscow, Russia
ORCID: 0000-0001-8041-151X, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0001-6169-717X, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ORCID: 0000-0002-2544-1131, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The article presents modern methods of rational use of associated petroleum gas. One of the oil-producing enterprises in the territory of Russia, «RN-Uvatneftegaz», which is a subsidiary of Rosneft, was considered. The article also presents the developed, taking into account climatic, geographic, economic and other factors, projects to increase the monetization of associated petroleum gas (APG) for the considered enterprise. The calculation of economic indicators for each project is given, which makes it possible to make a final decision on the effectiveness of the analyzed projects on the basis of a generalized indicator. The risks accompanying each of the proposed projects are considered. Based on the analysis of the results presented in this article, the most attractive option for increasing the monetization of associated petroleum gas for the «RN-Uvatneftegaz» enterprise was selected for all of the considered criteria.
KEYWORDS: increase of associated petroleum gas monetization, associated petroleum gas, rational use of associated petroleum gas associated petroleum gas, generation of electric power, wide fraction of hydrocarbons, dry stripped gas, underground gas storage, development of projects.
For citation: Klimenko E.T., Rostovtsev V.O., Solodilova A.E. COMPARATIVE ANALYSIS OF ASSOCIATED PETROLEUM GAS UTILIZATION TECHNOLOGIES AT THE FACILITIES OF ROSNEFT OIL COMPANY. Oil & Gas Chemistry. 2019, no. 2, pp. 30–35.
DOI:10.24411/2310-8266-2019-10206
KINETICS AND CATALYSIS
DIMETHYL ETHER CHEMISTRY: CATALYTIC SYNTHESIS OF 1,3-BUTADIENE IN THE PRESENCE OF HYDROGEN PEROXIDE (P. 36-42)
Anton L. Maksimov, Valentin F. Tretyakov, Rashid M. Talyshinskiy,
Ahmadsho M. Ilolov, Salambek N. Khadzhiev
A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia
E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
For the first time, direct catalytic synthesis of 1,3-butadiene from dimethyl ether was carried out in the presence of hydrogen peroxide. A conjugated mechanism for the formation of 1,3-butadiene in the presence of hydrogen peroxide is installed, as well as a positive initiating effect of its influence effect on the duration of reaction cycle of dimethyl ether conversion. The Prince condensation mechanism is shown taking into account the formation of radicals •OH and НО•2.
KEYWORDS: catalysis, DME, 1,3-butadiene, mechanism, prince condensation, formaldehyde, acetaldehyde, propylene, ethylene, butylenes, renewable alternative carbon-containing raw material, hydrogen peroxide.
For citation: Maksimov A.L., Tretyakov V.F., Talyshinsky R.M., Ilolov A.M., Khadzhiev S.N. DIMETHYL ETHER CHEMISTRY: CATALYTIC SYNTHESIS OF 1,3-BUTADIENE IN THE PRESENCE OF HYDROGEN PEROXIDE. Oil & Gas Cheуmistry. 2019, no. 2, pp. 36–42.
DOI:10.24411/2310-8266-2019-10207
Acknowledgments: The work was carried out within the framework of the State Task of IPS RAS.
OBTAINING VANADYL PORPHYRIN COMPLEXES BASED ON OIL AND APPLICATION IN CATALYTIC OXYGENATION OF OLEFINS (P. 43-45)
Zakhra E. Bayramova
Azerbaijan State University of Oil and Industry, AZ1010, Baku, Azerbaidjan
ORCID: https://orcid.org/0000-0002-7165-7232, E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
This article presents the results on the synthesis of petroleum vanadylporphyrin complexes by isolating a mixture of metal porphyrins from Azerbaijani oils and studying their catalytic properties. The mechanism of the oxidation reaction of cyclic olefins in the presence of vanadylporphyrin complexes has been studied. A method has been developed for obtaining individual porphyrin complexes of transition metals with respect to metal, starting from oil porphyrin concentrates based on the exchange reaction of hydrogen atoms by metal in the porphyrin cycle. The catalytic activity of the synthesized complexes was studied in the reaction of the oxygenation of cyclic olefins with molecular oxygen.
KEYWORDS: metalloporphyrins, oxidation, porphyrin complexes, cyclohexene, dioxygen adducts.
For citation: Bayramova Z.E. OBTAINING VANADYL PORPHYRIN COMPLEXES BASED ON OIL AND APPLICATION IN CATALYTIC OXYGENATION OF OLEFINS. Oil & Gas Cheуmistry. 2019, no. 2, pp. 43–45.
DOI:10.24411/2310-8266-2019-10208
