CONTENTS of journal "OIL & GAS CHEMISTRY" 1·2018 (Russia)
CHEMICAL TECHNOLOGIES AND PRODUCTS
EXPERIENCE IN DESIGNING OF THE GAS PROCESSING PLANT AS A PART OF THE PROCESSING COMPLEX OF ASSOCIATED PETROLEUM GAS FROM NORTH CASPIAN FIELDS BASED ON “STAVROLEN” LLC WITH APPLICATION OF RUSSIAN TECHNOLOGIES (P. 5-13)
ALEKPEROV V.YU., Dr. Sci. (Econ.), President, Chairman of the board
MAGANOV R.U., Senior Executive Vice President
NEKRASOV V.I., Cand. Sci. (Tech.), Presidential Adviser
GIMALETDINOV R.R., Vice President for Oil Refining, Petrochemistry, Gas Processing
PJSC “LUKOIL” (11, Sretensky Boulevard, Moscow, 101000, Russia).
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USMANOV M.R., Cand. Sci. (Tech.), General Director
OZHEGIN A.V., Head of Group 1 of the Production Control Processing Department
CHERNYSHOV A.N., Project Deputy Chief Engineer
“LUKOIL-Nizhegorodniinefteproyect” LLC (147 A, Maxim Gorky St., Nizhny Novgorod, 603006, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
This article describes design experience of the unit put into operation with capacity of 2.2 bln. nm3/year for low temperature processing of associated petroleum gas with unique capacity range (30-110%) with application of Russian technologies, materials and equipment corresponding to modern operation reliability and safety requirements. System approach implemented by PJSC “LUKOIL” for processing of hydrocarbons of the North Caspian fields allowed to achieve 95% associated petroleum gas recovery and to increase efficiency of the Petrochemical Plant of “Stavrolen” LLC by means of replacement of imported feedstock to own natural gas liquids and to provide independent electric and thermal power source with dry stripped gas.
KEYWORDS: PJSC “LUKOIL”, full-field development of the North Caspian, associated petroleum gas, recovery rate, “Stavrolen” LLC, economic efficiency increase, gas processing plant, adsorption dehydration, low temperature separation, natural gas liquids, dry stripped gas, electric power generation, “LUKOIL-Nizhegorodniinefteproyect” LLC.
METHODS OF OBTAINING SYNTHESIS GAS FOR METHANOL PRODUCTION (P. 14-19)
GIMAEVA A.R., Cand. Sci. (Tech.), Associate Prof. of Department of Transport and Storage of Oil and Gas
KHASANOV I.I., Cand. Sci. (Tech.), Associate Prof. of Department of Transport and Storage of Oil and Gas
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Republic of Bashkortostan, Russia) E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
At present, natural gas, first of all, is an energy raw material. At the same time, a large part of it is sent for processing. Chemical processing of natural gas can become one of the strategic tasks that will allow Russia to give impetus to the creation of fundamentally new Russian technologies. One of the directions of processing of gas hydrocarbon raw materials is the production of methanol, which is one of the most important large-tonnage products of organic synthesis. In the article methods of obtaining synthesis gas necessary for the production of methanol are considered. The most common methods for obtaining synthesis gas are given, the advantages and disadvantages of each method are analyzed.
KEYWORDS: synthesis gas, natural gas, methane, conversion.
DIENESYNTHESIS IN SUPERCRITICAL CONDITIONS (P. 20-24)
GAETKULOVA G.K., Student
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
PAS’KO P.A., Postgraduate Student
TALIPOV R.F., Dr. Sci. (Chem.), Prof.
VAKULIN I.V., Dr. Sci. (Chem.), Prof.
Bashkir State University (32, Validy St., 450076, Ufa, Russia)
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SHIRIYAZDANOV R.R., Cand. Sci. (Tech.), Assoc. Prof.
DAVLETSHIN A.R., Cand. Sci. (Tech.), Assoc. Prof.
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.,
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ABSTRACT
The results of a study of the process of diene synthesis (Diels-Alder reaction) between piperylene and ethylene using supercritical fluid technologies are presented. The cycloaddition reaction is directed to the production of methylcyclohexene, which, in turn, is used for the synthesis of isoprene. A series of experiments were carried out at various temperatures, pressures, and component ratios. The highest yield of the methylcyclohexene is observed at the following parameters of process: temperature 300 ° C, pressure 5.27 MPa and piperylene: ethylene ratio is equal to 1:10.
KEYWORDS: supercritical fluid, methylcyclohexene, isoprene, Diels-Alder reaction, piperylene, olefins, diene synthesis, cyclic compounds, monomer, synthetic isoprene rubber.
SYNTHESIS AND RESEARCHING OF PROPERTIES OF AZO DYES AND AZO PIGMENTS BASED ON POLYPHENOLS OF DIFFERENT GENESIS (P. 25-28)
КOBRAKOV К.I., Dr. Sci. (Chem.), Prof., Head of Department of Organic Chemistry
KUZNETSOV D.N., Cand. Sci. (Chem.), Associate Prof. of Department of Organic Chemistry
RUCHKINA А.G., Cand. Sci. (Chem.), Associate Prof.of Department of Organic Chemistry
NADYRBAEV I.А., Postgraduate of Department of Organic Chemistry
KLYAUZOVA A.V., Magister of Department of Organic Chemistry
Russian State University named by A.N. Kosygin (Technologies. Design.Art). (1, Malaya Kaluzhskaya St., 119991, Moscow, Russia).
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ABSTRACT
In this article there are given literary and own experimental data about synthesis and properties of azo compounds based from synthetic polyatomic phenols – 1,2,3-trihydroxybenzene (pyrogallol), 1,3,5-trihydroxybenzene (phloroglucinol) and 2,4,6-trihydroxytoluene (methylphloroglucinol). There discussed possibilities of utilizing obtained results for synthesis of analogues of azo compounds with using of some individual polyphenols of nature origin and their mixtures derived from plant extracts.
KEYWORDS: polyphenols, azo dyes, azo pigments, natural dyes, pyrogallol, phloroglucinol, methylphloroglucinol.
KINETICS AND CATALYSIS
OIL METALPORPHYRINES - CATALYSTS OF SELECTIVE OXYGENATION OF UNDEFINIED HYDROCARBONS (P. 29-32)
AGHAGUSEYNOVA M.M., Dr. Sci. (Chem.), Prof. of the Department Chemistry and Technology of Inorganic Substances
AMANULLAYEVA G.I., Assoc. Prof. of the Department Chemistry and Technology of Inorganic Substances
BAYRAMOVA Z.E., Doctoral Student of the Department Chemistry and Technology of Inorganic Substances
Azerbaijan State University of Oil and Industry (20, Azadlyg Ave., AZ1010, Baku, Azerbaijan Republic). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
In the development of new highly selective methods of hydrocarbons oxygenation at moderate temperatures, special attention is paid to the use of porphyrin complexes of transition metals as catalysts. This article presents the results on the synthesis of petroleum metalloporphyrin complexes of transition metals by separating a mixture of metalloporphyrins from Azerbaijan oils and study of their catalytic properties. A method for the preparation of metal-specific porphyrin complexes of transition metals proceeding from metal-porphyrin oil concentrates based on the reaction of hydrogen atoms exchange with a metal in the porphyrin cycle was developed. The mechanism of the reaction of olefin oxidation in the presence of metalloporphyrin complexes was studied.
KEYWORDS: petroleum metalloporphyrin complexes, unsaturated hydrocarbons, transition metals, molecular oxygen.
TRANSFORMATION OF N-HEXANE AND STRAIGTRUN GASOLINE ON TO MODIFIED PENTASYLES (P. 33-36)
MAMEDOV S.E., Dr. Sci. (Chem.), Prof. of the Department of Physical and Colloid Chemistry
АKHMEDOVA N.F., Cand. Sci. (Chem.), Researcher of the Laboratory of Metal Complex Catalysts
MIRZALIYEVA S.E., Cand. Sci. (Chem.), Assoc. Prof. of the Department of Physical and Colloid Chemistry
MIRZAI D.I., Dr. Sci. (Chem.), Prof. of the Department of Physical and Colloid Chemistry
AKHMEDOV E.I., Dr. Sci. (Chem.), Prof., Head of the Department of Physical and Colloid Chemistry
AZMAMEDOVA KH.М., Cand. Sci. (Chem.), Laboratory Assistant of the Department of Physical and Colloid Chemistry
DADASHEVA S.S., Postgraduate Student of the Department of Physical and Colloid Chemistry
Baku State Univercity (23, Academic Zahid Xalilov St., AZ1148, Baku, Azerbaijan Republic). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
Effect of the nature and concentration of modifiers (Cu, Fe, Zn) on catalytic properties of pentasyles in n-hexane transformation and under refining the straight-run gasoline without hydrogen has been studied. It was confirmed that the highest flavoring and isomerization activity has n-pentasyle modified with Cu. It was found that the best catalyst among the investigated Cu-containing catalysts has 2,0 % mass. Cu-n-pentasyle which give the ability to obtain the gasoline component at 3800С temperature with 85 octane number and the yield of liquid catalyst equal 74,5%.
KEYWORDS: n-hexane, pentasyls, isomerization, straight-run gasoline, octane number.
MODELING OF OIL AND GAS GEOSYSTEMS
MATHEMATICAL METHODS AND MODELLING OF HYDROCARBON SYSTEMS WHEN ASSESSING THE GEOLOGICAL AND ECONOMIC RISKS OF EXPLORATION FOR OIL AND GAS (P. 37-44)
KERIMOV V.YU., Dr. Sci. (Geol.-Min.), Prof., Head of the Department of Theoretical Basics of Prospecting and Exploration of Oil and Gas
Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy Pr., 119991, Moscow, Russia).
Russian State Geological prospecting University (23, Miklouho-Maklay’s St., 117997, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
BAKHTIZIN R.N., Dr. Sci. (Ph.-m.), Prof., Rector
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Republic of Bashkortostan, Russia).E-mail: rektor@rusoil.net
BONDAREV A.V., Cand. Sci. (Geol.-Min.), Associate Prof., Deputy Head of the Department of Theoretical Basics of Prospecting and Exploration
of Oil and Gas
Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy Pr., 119991, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The article analyzes mathematical methods and modeling of hydrocarbon systems in the evaluation of geological and economic risks of exploration for oil and gas. It is shown that risks are uncertain events or conditions that, in case of occurrence, negatively affect at least one goal of the project.
KEYWORDS: risks, modeling, exploration, analysis, efficiency.
MODELING STRATEGY OF HYDROCARBON SYSTEMS AT DIFFERENT STAGES OF GEOLOGICAL EXPLORATION FOR OIL AND GAS (P. 45-49)
KERIMOV V.YU., Dr. Sci. (Geol.-Min.), Prof., Head of the Department of Theoretical Basics of Prospecting and Exploration of Oil and Gas
MUSTAEV R.N., Cand. Sci. (Geol.-Min.), Associate Prof. of the Department of Theoretical Basics of Prospecting and Exploration of Oil and Gas
Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy Pr., 119991, Moscow, Russia).
Russian State Geological prospecting University (23, Miklouho-Maklay’s St., 117997, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.,
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SERIKOVA U.S., Cand. Sci. (Tech.), Associate Prof. of the Department of Theoretical Basics of Prospecting and Exploration of Oil and Gas
Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy Pr., 119991, Moscow, Russia).
ABSTRACT
The article deals with the modeling of hydrocarbon systems at different stages of exploration for oil and gas. It shows the tasks of modeling and research facilities at the regional, prospecting and evaluation stages of exploration work. The maps of the forecast accumulation, sources of generation and migration routes on Sakhalin shelf are given. A geological model of the northeastern part of the Black sea is presented, as well as projected oil and gas accumulation zones and traps in the northeastern part of the Black sea.
KEYWORDS: modeling, hydrocarbon systems, hypotheses, exploration, stages.
