CONTENTS of journal "OIL & GAS CHEMISTRY" 2·2017 (Russia)
DEVELOPMENT STRATEGY
NEW DEVELOPMENT TRENDS OF THE WORLD OIL-GAS-CHEMICAL INDUSTRY AND RUSSIAN REALIA (P. 5-12)
BRAGINSKY O.B., Dr. Sci. (Econ.), Prof., Head of the Laboratory Strategies for the development of industry complexes FGBUN Central Economics and Mathematics Institute of Russian Academy of Sciences (47, Pr. Nakhimovsky, 117418, Moscow, Russia).
ABSTRACT
The author has researched new trends in the development of the world oil and gas chemical industry projected to the years until 2025. In the article, there have been revealed emerging development trends in the development primarily in the functioning of world petrochemical industry in conditions of reduced gas and oil prices. The author has noted a further shift in the location of the industry in the Asia-Pacific region and the Middle East region, new technological shifts, and the impact of the US shale revolution. Author makes it obvious that Russian oil and gas chemical industry lags behind not only developed but also rapidly developing countries. The program of long-term development of oil and gas chemistry in Russia, incl. new large oil and gas chemical enterprises development projects is analyzed in the article. An approach to the selection of the priority projects in conditions of limited financial resources is proposed.
KEYWORDS: оil and gas chemical industry, development trends, strategy, projects.
CHEMICAL TECHNOLOGIES AND PRODUCTS
CONCENTRATIONS OF VANADIUM AND NICKEL AND THEIR RATIO IN HEAVY OIL RESINS (P. 13-16)
ABILOVA G.R., Postgraduate Student
SINYASHIN K.O., Assistant Director
TAZEEVA E.G., Junior Researcher
BORISOVA YU.YU., Cand. Sci. (Chem.), Researcher
MILORDOV D.V., Cand. Sci. (Chem.), Junior Researcher
YAKUBOVA S.G., Cand. Sci. (Chem.), Researcher
YAKUBOV M.R., Cand. Sci. (Chem.), Assoc. Prof., Deputy Director for Research
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences (8, Arbuzov St., 420088, Kazan,
Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.; E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript..
ABSTRACT
The resins of heavy oils from different oilfields, in which the total content of vanadium and nickel range from 0.0049 to 0.1795 wt %, have been studied. As the vanadium and nickel content in heavy oils increases, the concentration of these metals in the resins increases too. In the resins of heavy oils the vanadium content varies in the range of 0,003–0,14 wt %, while the nickel content lies in the range of 0,0011–0,0143 wt%. It has been shown that when vanadium content in the resins of heavy oil is increased the asphaltenes/resins ratio tends to decrease. The results obtained for vanadium and nickel content in the resins should allow to predict the distribution of these metals in products of secondary oil refining processes applied to heavy oils of various compositions.
KEYWORDS: heavy oil, resins, vanadium, nickel.
SYNTHESIS OF HIGHER ALKYL NAPHTHALENES AND ESTERS OF ALKENYLSUCCINIC ACID AS A BASIS OF LUBRICANT OILS (P. 17-21)
GABIDULLINA Z.K., Master Student
BAZARGULOVA R.K., Master Student
GINDULLINA L.R., Master Student
KARIMOVA A.R., Postgraduate Student
PROKAEV G.L., Master Student
SHADRINA A.E., Postgraduate Student
KHAMZIN YU.A., Postgraduate Student
DAVLETSHIN A.R., Cand. Sci. (Tech.), Assoc. Prof.
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.; E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The work presents the results of the survey f the synthesis of alkyl naphthalenes and esters of alkenylsuccinic acid as components of synthetic lubrication agents. Alkyl naphthalenes are synthesized with the use of high-module zeolite-containing catalysts on the basis of Y-zeolites within the temperature range from 120 to 210°С. It has been established that the maximum yield of the product composes 62,49 % mass. In order to receive ester of alkenylsuccinic acid the alkenylsuccinic anhydride was preliminaty synthesized with the use of ditert-butyl peroxide as a
catalyst. Correlated the viscosity/temperature properties of the compositions of the basis of synthetic oils on the basis of polyalfaolefin synthetic oil production and obtained vicinal diesters.
KEYWORDS: alkenyl succinic anhydride, alkylnaphthalene, zeolites, synthetic base, lubricating oil, olefin, naphthalene.
MATHEMATIZATION AND MODELLING – BASE OF ENGINEERING CHEMICAL AND TECHNOLOGICAL SPECIALTIES (P. 22-26)
BAKHTIZIN R.N., Dr. Sci. (Ph.-M.), Prof., Rector
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Republic of Bashkortostan, Russia).E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
KERIMOV V.YU., Dr. Sci. (Geol.-Min.), Prof., Head of the Department of Theoretical Basics of Prospecting and Exploration of Oil and Gas
Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy Pr., 119991, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
SHEMYAKOV A.O., Cand. Sci. (Tech.), Associate Prof., Head of Innovation, Strategy and Communications Department
Moscow Aviation Institute (National Research University) (4, Volokolamskoe Highway, 125993, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
GYUL’MALIEV A.M., Dr. Sci. (Chem.), Prof., Chief Researcher
A.V. Topchiev Institut of Petrochemical Synthesis (TIPS RAS) (29, Leninskiy prosp., 119991, Moscow, Russia).
MOVSUM-ZADE N.CH., Cand. Sci. (Tech.), Researcher
Institute of information technology of NAS of Azerbaijan (9, B. Vahabzade, Baku, Azerbaijan Republic, AZ1141).
ABSTRACT
The paper presents the main mathematical methods used in various courses in oil field specialties, modeling of prospecting and exploration of oil and gas fields, as well as the optimization at processes description for the petrochemical industry. It proposes methods of use of statistical planning to determine the optimal parameters of the reactions. It shows the calculations of the parameters of recycling, and the use of mathematical methods to determine the chemical, physical and thermodynamic parameters of molecules and systems that can not be obtained at the same time by other methods. This work proposes management model of different oil and gas processes, reactions and complexes.
KEYWORDS: modeling, optimization, calculations, mathematical methods, statistical planning, management processes, recirculation, recirculation processes.
DRY STRIPPED GAS IS THE PROCESS OF TURNING INTO FERTILIZER (P. 27-30)
BORODIN A.V., Cand. Sci. (Tech.), Head of Logistics Department
Gazprom Neft PJSC (3-5, Pochtamtskaya St., 190000, St. Petersburg, Russia).
SIMANDUYEV D.S., Bachelor
GUSEYNOVA S.N., Postgraduate Student
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The paper presents the possibility of utilization of dry stripped gas (DSG) in chemistry, petrochemistry and oil production. Attention is paid to the advantages of gas-lift method of operating oil wells using DSG. Also this paper presents the process of obtaining practically useful products: plasticizers, rubber, fertilisers for agriculture.
KEYWORDS: associated petroleum gas, dry stripped gas, gas-lift method of operating oil wells, mineral fertilizers.
HYDRODYNAMIC PROCESSES IN REACTORS OF CATALYTIC RIFORMING (P. 31-39)
DUDAREVA A.A., Master Student
SMOLNIKOVA Т.В., Cand. Sci. (Tech.), Assoc. Prof. of the Department of Gas Chemistry and Modeling of Chemical Processes
DAVLETSHINA A.Z., Master Student
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia).
ABSTRACT
At present, most industrial enterprises of the Russian petrochemical and gas complex use a reactor that was manufactured more than 30 years ago and it becomes necessary to replace them with more modern, convenient, functional and economically efficient ones. This article deals with the design, types, internal arrangement of reactors. The model of the reactor modeled with the help of the multifunctional program SolidWorks is given, which allows drawing a reactor in 3D format, selecting the material of execution, dimensions, connecting parts in the assembly. Various packages of the SolidWorks program made it possible to calculate the hydrodynamic processes inside the reactor.
KEYWORDS: catalytic reforming, catalytic processes, process catalysts, catalytic reforming reactors, SolidWorks.
THE FORMATION AND DEVELOPMENT OF THE PYROLYSIS PROCESS AT BAKU REFINERIES (P. 40-45)
AKHMADOVA KH.KH., Dr. Sci. (Tech.), Prof. of the Department of Chemical Technology of Oil and Gas
Grozny State Oil Technical University (100, Kh.A. Isaeva Av., 364051, Chechen Republic, Grozniy, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
SYRKIN A.M., Cand. Sci. (Chem.), Prof. of the Department of General and Analytical Chemistry
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Republic of Bashkortostan, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
SHTEPA D.V., Junior Researcher of the Department of General Chemistry
Lomonosov Moscow State University, Faculty of Chemistry (1-3, Leninskiye Gory, 119991, Moscow, Russia).
MOVSUM-ZADE N.CH., Cand. Sci. (Tech.), Researcher
Institute of information technology of NAS of Azerbaijan (9, B. Vahabzade, Baku, Azerbaijan Republic, AZ1141).
ABSTRACT
The article shows that Azerbaijan has a rich history of development and use of hydrocarbons, and the contribution of Baku to the formation and development of Russian and world oil industry is very significant. It distinguishes the basic stages of development of oil refining industry of Azerbaijan and provides a brief overview on the formation processes of thermal cracking, reforming and pyrolysis at the Baku refinery. Besides, the article presents historical chronicle of the research of the Caucasian oil, which was held by many prominent Russian scientists and engineers that contributed to the formation of the chemical processing areas of the Baku oil.
KEYWORDS: Azerbaijan, Baku, Baku oil refineries, oil, field, installation, oil refineries, distillation cubes, equipment thermocracking, riforming, pyrolysis, technology, modernization, reconstruction.
MONITORING, SIGNALING, MEASURING AND RECORDING OF PETROLEUM PROCESSES AND THEIR PHASED DEVELOPMENT (P. 46-49)
KHASANOV I.I., Cand. Sci. (Tech.), Associate Prof. of Department of Transport and Storage of Oil and Gas
LOGINOVA E.A., Engineer.
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Republic of Bashkortostan, Russia) E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
Control measuring instruments and devices in the oil and gas industry are considered in this paper. The stages of their development, modernization are briefly presented. Electromechanical devices (mainly telemechanics) are presented, the introduction of which made it possible to measure a number of parameters at a distance. The introduction of these devices into the oil and gas industry is shown, which led to a more reliable operation of all systems. It is shown that the introduction of new measuring systems and the introduction of new methods for monitoring parameters led to the creation of many directed and multifunctional telemechanical complexes. The example of the pressure sensor is frequency, the principle of its operation and the possibility of its use on oil field.
KEYWORDS: control, automation, measuring instruments, sensor, converter.
KINETICS AND CATALYSIS
RESEARCH OF THE CONFORMITY BY OLEFINS MANUFACTURING USAGE OF SUPERACID CATALYSTS (P. 50-53)
LICHMANOV A.A., Master Student
GABIDULLINA Z.K., Master Student
MULLAKHMETOVA G.A., Master Student
KARIMOVA A.R., Postgraduate Student
SHADRINA A.E., Postgraduate Student
KHAMZIN YU.A., Postgraduate Student
SHERSTOBITOVA A.K., Student
DAVLETSHIN A.R., Cand. Sci. (Tech.), Assoc. Prof.
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.;
E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The present work shows the results of the research of conversion of methanol to light olefins in wide temperature range with the use of superacid zeolite-containing catalyst of pentasil structure.
KEYWORDS: zeolite, methanol, olefin, ethylene.
INVESTIGATION OF THE PROCESS OF GOUDRON CRACKING IN THE PRESENCE OF CATALYSTS ON THE BASIS OF TUNGSTEN CARBIDE (P. 54-57)
MOROZOV M.A., Postgraduate Student
AKIMOV A.S., Cand. Sci. (Chem.), Junior Researcher
Institute of petroleum chemistry SB RAS (4, Akademichesky Avenue, 634055, Tomsk, Russia)
ZHURAVKOV S.P., Cand. Sci. (Chem.), Chief Technologist
National Research Tomsk Polytechnic University (30, Lenin Avenue, 634050, Tomsk, Russia)
VOSMERIKOV A.V., Dr. Sci. (Chem.), Prof., Director
FEDUSHCHAK T.A., Cand. Sci. (Chem.), Senior Researcher
Institute of petroleum chemistry SB RAS (4, Akademichesky Avenue, 634055, Tomsk, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
Russia ranks third in the world in terms of stocks of heavy oil feedstock. The exhaustion of deposits of light and medium oils makes it necessary to increase the processing of heavy, as well as residual petroleum feedstock to increase the depth of oil refining. Increase the depth of oil processing possible in various ways, one of which is the use of new efficient catalysts, resistant to corrosion, poisoning and coking. Tungsten carbide, as corresponding to the declared requirements, was selected as a promising material for the catalysts for cracking of heavy oil feedstock. The effect of tungsten carbide powders and the temperature of their calcination on the composition of the cracked products of heavy oil feedstock has been studied, and optimal conditions for calcination have been determined. The high catalytic activity of WC powders calcinated at 420 °C is shown. Using various methods of physical and chemical analysis, tungsten carbide, as well as gas, liquid and solid cracking products were investigated.
KEYWORDS: processing, heavy petroleum feedstock, tungsten carbide, fuel fractions, cracking.
OUR VETERANS
YULIY KOLBANOVSKIY: I CAN CONSIDER MYSELF AS A HAPPY MAN (P. 58-60)
