CONTENTS of journal "OIL & GAS CHEMISTRY" 1·2017 (Russia)

45 YEARS OF SUCCESS! (P. 5)

GAS SULFUR: PROBLEMS AND SOLUTIONS

CARL FRIEDRICH CLAUS – INVENTOR OF ELEMENTAL SULFUR FROM HYDROGEN SULPHIDE PRODUCTION PROCESS (P. 6-9)
GOLUBEVA I.A., Dr. Sci. (Chem.), Prof. of the Department of  Gaschemistry
GEYASI P.A.F., Student, Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy prosp., 119991, Moscow, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
The stages of creating Claus process aredescribed. The basic applications of sulfur gas are considered. The information about inventor of the gas sulfur production process Carl Friedrich Claus’s biography is given.
KEYWORDS: sulfur, Claus process, sulfur oxidation, sulfur production, Carl Friedrich Claus, biography.

CHEMICAL TECHNOLOGIES AND PRODUCTS

STERICALLY HINDERED PHENOLS AS ANTIOXIDANT, ANTICORROSION AND ANTIMICROBIAL ADDITIVES TO MINERAL LUBRICATING OILS (P. 10-13)
KOLCHINA G.Yu., Cand. Sci. (Chem.), Assistant Prof. of the Department of Chemistry and Chemical Technology, Federal State-Funded Educational Institution of Higher Professional Education, Sterlitamak branch of Bashkir State University (47a, Lenin st., 453103, Sterlitamak, Republic of Bashkortostan, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
TUHVATULLIN R.F., Postgraduate student of the Department of General and Analytical Chemistry, Ufa State Oil Technical University (USPTU) (1, Kosmonavtov st., 450062, Republic of Bashkortostan, Ufa, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
BABAEV E.R., Cand. Sci. (Chem.), Researcher, Institute of Chemistry of Additives. Acad. Kuliev A.M. National Academy of Sciences of Azerbaijan (kv. 2062, Beyukshorskoe highway, AZ 1029, Baku, Republic of Azerbaijan). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
MOVSUMZADE E.M., Corresponding Member Russian Academy of Education, Dr. Sci. (Chem.), Prof., Adviser to the Rector, Ufa State Oil Technical University (USPTU) (1, Kosmonavtov st., 450062, Republic of Bashkortostan, Ufa, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
It was found that the sulfur-containing derivatives of hindered phenols have a more effective antioxidation, anticorrosion and antimicrobial properties. Effective shielding the hydroxyl group in the substituted phenols, along with applicable tret-butyl radicals, administration can be carried out in o-position of the phenol molecule α-methylbenzyl groups. Sterically hindered phenols (obtained from them and the phenoxide radicals) are potent inhibitors of oxidation of various organic materials. It is shown that their effectiveness as inhibitors of oxidation depends on the structure, in particular, are the determining factors of the structure of alkyl groups and character p-substituent. It was established that one of the most effective methods is the use of hindered phenols and sulfides, which cause the destruction of hydroperoxides to molecular products and thereby prevent the possibility of degenerate branching chain oxidation (a synergistic effect).
KEYWORDS: sterically hindered phenols, additives, lubricants, oxidation mechanism, antioxidantes, inhibitory effect, synergistic effect.

COMPARATIVE ANALYSIS OF MODULAR SETTINGS TECHNOLOGY OF THE HELIUM EXTRACTION OUT OF NATURAL GAS (P. 14-18)
MNUSHKIN I.A., Cand. Sci. (Tech.), General Director
EROCHIN E.V., Postgraduate Student, Process Engineer, LLC «Research and Design Institute of Oil and Gas «PETON» (60/1, avenue Salavat Yulaev , Ufa, Republic of Bashkortostan, Russia).
SYRKIN A.M., Cand. Sci. (Chem.), Prof. of the Department of General and Analytical Chemistry, Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
The article gives the comparison of the efficiency of cryogenic, membrane and combination technology of modular settings of helium extraction out of natural gas selected from the mainline gas pipeline "Power of Siberia" on the fuel supply compressor stations and human settlements.
KEYWORDS: natural gas, helium, fuel gas, mainline gas pipeline, modular facility, cryogenic, membrane, combined technology.

COMPLEX FOR OBTAINING SYNTHESIS2GAS FOR SMALLTONNAGE PRODUCTION OF METHANOL (P. 19-26)
ZAGASHVILI YU.V., Dr. Sci (Tech.), Prof., General Director, CEO of  LLC "VTR" (9-587,  Morskaya Naberezhnaya, 199226, Saint-Petersburg, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
EFREMOV V.N., Cand. Sci. (Tech.), Chief Researcher, LLC «DELTA-SINTEZ» (3, Berezhnoi St., Novomoskovsk, 301650, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
KUZMIN A.M., Cand. Sci. (Tech.), General Director, CEOLLC «GSG» (15/1/49, Olgi Forsh St., 195297, Saint-Petersburg, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
LISCHINER I.I., Cand. Sci. (Chem.), Head of  Laboratory, Joint Institute for High Temperatures of the Russian Academy of Sciences (13/2, Ijorskaya St., 125412, Moscow, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
The technology of generating synthesis gas for low-tonnage methanol production based on partial oxidation of hydrocarbon gases in high-temperature gas generator is developed. The functional scheme of the complex preparation of the synthesis gas and the features of the proposed technology are considered. In addition, there is information about of the description of the construction and technical characteristics of the main complex unit. The weight and size characteristics of the generator allow creating a transportable modular construction of the complexes for preparation the synthesis gas. The results of thermodynamic and balance calculations for small-scale plant for the production of methanol with the capacity of 5 000 tons a year working on the components of "natural gas – enriched air" are presented.
KEYWORDS: synthesis gas, methanol, partial oxidation, hydrocarbon gases, gas-generator, small-scale plants, the oxidizer / fuel ratio.

HYDROGENATION TREATING OF PETROCHEMICAL PRODUCT AND HEAVY PETROLEUM RESIDUES UNDER FAST ENGINEERING® PROCESS (P. 27-35)
ASTANOVSKY D.L., Cand. Sci. (Tech.), President
ASTANOVSKY L.Z., Vice President company
KUSTOV P.V., Head of Engineering department, FAST ENGINEERING Ltd., (Novocheremushkinskaya 21-1-191, Moscow, 117218, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
Traditional processes for hydrogenation treating of petrochemical product and heavy petroleum residues and FAST ENGINEERING®process with using created catalytic reactors, heat exchanger and mass-transfer apparatuses of a new generation are presented. Presented process of petrochemical product hydrotreating and hydrocracking allows to put down hydrogen consumption at the expense of its loss reduction, increase catalyst service life, raw material space velocity, decrease catalyst consumption and weight and dimensional characteristics of apparatuses, provides required degree of purification of petrochemical product from sulfur and nitrogen as well as required deep conversion into high quality light fractions, considerable reduce of capital investment and energy saving under operation.
KEYWORDS: oil and gas chemistry, hydrogenation treating, hydrocracking, hydrotreating, heavy petroleum residues deep conversion, hydrogen, catalytic reactor, heat exchanger and mass-transfer apparatus.
 
INHIBITION OF THE PARAFFIN DEPOSITS BY USING OF COPOLY (STYRENE2MALEIC ANHYDRIDE) TO BE MODIFIED BY AMINE (P. 36-39)
PUZIN YU.I., Dr. Sci. (Chem.), Prof. of the Department of General and Analytical Chemistry. E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
MASTOBAEV B.N., Dr. Sci. (Tech.), Prof., Head of  Department of  Transport and Storage of Oil and Gas. E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
PUZIN P.YU., Graduate Student of  Department of  Transport and Storage of Oil and Gas. E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
SMOLNIKOVA T.V., Cand. Sci. (Chem.), Assoc. Prof. of  the Department of Gas Chemistry and Modeling of  Chemical Processes. E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Republic of Bashkortostan, Russia).
ABSTRACT
Methods of chemical modification of mono – and diamines industrial polymer – copolymers(styrene-maleic anhydride)and derivatives obtained polymeric reagents suitable for reducing the rate of formation of asphaltic and paraffin deposits APD. The estimated composition of the obtained polymers, the calculated degree of modification, proposed a formula reflecting the composition of the macromolecules. Evaluated the effect of modified polymers on the formation of paraffin by the method of «cold core». It was found that the addition of polymers have been obtained in small quantities significantly reduces the amount of formed APD. The connection structure of the polymer and the degree of inhibition of formation of APD. Suggested that the mechanism of inhibition of modified copolymers represent additive complex action.
KEYWORDS: asphalt-tar-paraffin deposits, formation of AFS, methods of fighting with AFS, styromal, amidation of styromal.

ANALYSIS AND OPTIMIZATION OF HEAT TRANSFER EQUIPMENT OF ATMOSPHERIC AND VACUUM DISTILLATION OF OIL REFINING (P. 40-46)
DOBROVA A.A., Graduate Student
ILCHIBAEVA A.K., Graduate Student
HIDIYATULLIN A.S., Graduate Student
HARITSKY D.K., Graduate Student
ANTIPIN O.S., Graduate Student
KHAFIZOVA S.R.,  Cand. Sci. (Chem.), Senior Lecturer of the Department of Gas Chemistry and Modeling of Chemical Processes
RUDNEV N.A., Cand. Sci. (Tech.), Assoc. Prof. of the Department of Gas Chemistry and Modeling of Chemical Processes, Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
Increased utilization of secondary energy resources, maximum use of heat recovery, and optimization of operating modes of process units – one of the priority directions for increase the energy efficiency of oil refineries. This article discusses the analysis, optimization of the existing heat exchange network using the software Aspen Hysys V8.8, Aspen Exchanger Design, Rating V8.4, and proprietary software.
KEYWORDS: fuel and energy resources, heat recovery, energy saving, energy efficiency, pinch analysis, pre-heating of fuel, heat exchange equipment.

THE SYNTHESIS OF NEW ANTIOXIDANT  ADDITIVES FOR FUELS AND LUBRICATING OILS ON THE BASIS OF PHLOROGLUCINOL (P. 47-49)
ALEKSANYAN K.G. Cand. Sci. (Chem.), Assoc. Prof., Department of Organic Chemistry and Petroleum Chemistry
YARULLIN N.R. Student, Department of Organic Chemistry and Petroleum Chemistry
SALMANOV YU.S. Student, Department of Organic Chemistry and Petroleum Chemistry
NALETOVA A.V. Student, Department of Organic Chemistry and Petroleum Chemistry,
Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy Pr., 119991, Moscow, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
In this study the methods of synthesis are developed and obtained the new derivatives of phloroglucinol (PG) and methylphloroglucinol (MPG) which tested as the antioxidant additives. We obtained diaminomethylphloroglucinol (DAMPG) and triaminopholoroglucinol (TAPG) with reduction of dinitrophloroglucinol and trinitrophloroglucinol, respectively. The DAMPG was tested as an antioxidant.
KEYWORDS: antioxidant additives, phloroglucinol, methylphloroglucinol, dinitromethylphloroglucinol, diaminomethylphloroglucinol.

KINETICS AND CATALYSIS

EFFECT OF HIGH-TEMPERATURE TREATMENT OF A GACONTAINING ZEOLITE ON ITS ACIDIC AND CATALYTIC PROPERTIE IN THE COURSE OF PROPANE AROMATIZATION (P. 50-53)
VOSMERIKOVA L.N., Cand. Sci. (Chem.), Senior Researcher
RYABOVA N.V., Lead Engineer
VOSMERIKOV A.V., Dr. Sci. (Chem.), Head of the Laboratory, Institute of petroleum chemistry SB RAS (4, Akademichesky Avenue, 634055, Tomsk, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
A Ga-aluminosilicate of ZSM-5 zeolite synthesized from alkaline alumina-silica gels via hydrothermal crystallization is thermally pretreated at different temperatures in the air atmosphere. The acidic and catalytic properties of the prepared samples are investigated during the conversion of propane into aromatic hydrocarbons. The dependence of activity and selectivity of galloaluminosilicate on its calcination temperature is determined. Experimental investigations made it possible to determine the conditions for preliminary heat treatment of the catalyst permitting its maximal aromatization activity in the course of propane conversion.
KEYWORDS: Ga-alumosilicate, aromatization, propane, conversion, selectivity, acidity.

NEW RESEARCH METHOD OF THE SURFACE ACIDITY OF THERMAL DESORPTION OF AMMONIA IN HETEROGENEOUS CATALYSTS BY ELECTROMAGNETIC MICROWAVE RADIATION (P. 54-58)
ZULFUGAROVA S.M., Cand. Sci. (Chem.), Head Laboratory
ASKEROV A.G., Cand. Sci. (Chem.), Leading Researcher
GASANGULIEVA N.M., Cand. Sci. (Chem.), Leading Researcher
SHAKUNOVA N.V., Cand. Sci. (Chem.), Senior Researcher
ALESKEROVA Z.F., Senior Engineer
LITVISHKOV YU.N., Dr. Sci. (Chem.), Prof., Corresponding Member NAS of Azerbaijan, Institute of  Catalysis and Inorganic Chemistry of  the National Academy of Sciences of Azerbaijan (29, ave. Huseyn Javid, AZ 1143, Baku, Azerbaijan). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
TALYSHINSKY R.M., Dr. Sci. (Chem.), Leading Researcher, A.V. Topchiev Institut of Petrochemical Synthesis (TIPS RAS) (29, Leninskiy prosp., 119991, Moscow, Russia).
ABSTRACT
In work the new research method of surface acidity of heterogeneous catalysts based on thermal desorption from a surface of the studied samples of the adsorbed ammonia by the electromagnetic radiation in the microwave range are demonstrated. Technical opportunities of a method are shown on the example of a surface acidity research for samples Zn-B-P/γ-Al2O3/Al – in diethyl amine acylation catalyst by m-methyl-benzoic acid and SO4/ZrO2/γ-Al2O3–catalyst of hexene-1 dimerization. Unlike the known method of measurement of surface acidity by thermal desorption of the ammonia which is carried out by means of traditional sources of heating, the offered method favourably differs in uniform heating of all volume of the samples absorbing radiation, high speed and selectivity of heating, lack of temperature gradient and by that promotes express and productive carrying out experiments.
KEYWORDS: heterogeneous catalysis, acid centers, thermal desorption, ammonia, microwave oven radiation, range.

AWARD FOR OUTSTANDING WORKS IN THE FIELD OF CATALYSIS (P. 59)

JUBILEE DATES

STAR OF SCIENCE (P. 60)

ATMOSPHERE, WHICH PROTECT

Requirements to articles submitted for publication in the journal «Oil & Gas Chemistry» (P. 64)

 

 

Фотогалерея

КОНТАКТЫ

Индекс: 119313
Москва, улица Гарибальди, д. 4Г
Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.

Телефон редакции:
+7 (916) 593-05-29