CONTENTS of journal "OIL & GAS CHEMISTRY" 4·2016 (Russia)
NEWS (P. 7-8)
EXHIBITIONS, CONFERENCES, SEMINARS
ACTUAL PROBLEMS OF PETROCHEMISTRY (P. 9-11)
THE COVER THEME
THE RESULTS OF THE RAS ELECTIONS IN 2016 (P. 12-13)
CHEMICAL TECHNOLOGIES AND PRODUCTS
PROSPECTS OF FIELD GAS CHEMICAL TECHNOLOGIES USING NITROGEN-DILUTED SYNGAS (P. 14-23)
Arutyunov V.S., Dr. Sci. (Chem.), Prof., Head of Laboratory of Hydrocarbon Oxidation. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Savchenko V.I., Dr. Sci. (Chem.), Prof., Chief Researcher. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Sedov I.V., Cand. Sci. (Chem.), Head of Department of Chemistry and Technology. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript. , Institute of Problems of Chemical Physics of Russian Academy of Sciences (IPCP RAS) (1, Academician Semenov avenue, Chernogolovka, Moscow region, 142432, Russia)
Lomonosov Moscow State University (MSU), Faculty of Fundamental Physical and Chemical Engineering (1, page 51, 1 educational building, Leninskiye Gory, Moscow, GSP-1, 119991, Russia)
ABSTRACT
The possibility of developing of inexpensive and economically effective low-scale technologies for conversion of natural and associated gases directly at field conditions into liquid hydrocarbon chemicals using low-cost nitrogen containing syngas was analyzed. The principal advantages of using nitrogen containing syngas were outlined. Among them are the absence of necessity in expensive units for separation of air which also involve the increasing danger of explosion at field conditions, as well as the possibility of more stable and productive synthesis of liquid products using nitrogen containing syngas. The prospect methods of production of inexpensive nitrogen containing syngas are also were discussed.
KEYWORDS: natural gas, associated oil gas, conversion, syngas, Fisher-Tropsch process, synthetic hydrocarbons, methanol, dimethyl ether, lowscale thechnologies.
DEVELOPMENT OF COMPETITIVE COMPOUNDINGS OF MISCIBLE CUTTING FLUIDS (P. 24-26)
Tonkonogov B.P., Dr. Sci. (Chem.), Prof., Head of Department of Chemistry and Technology of Lubricants and Chemmotology. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Bagdasarov L.N., Cand. Sci. (Tech.), Assoc. Prof. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Agabekov S.S., Graduate Student. . E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Stakhiv V.I., Student. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript. , Gubkin Russian State University of Oil and Gas (65, korp.1, Leninskiy prosp., 119991, Moscow, Russia).
ABSTRACT
In the course of work the selection and optimization of the emulsol chemical composition were produced intended for 2-4% water microemulsion with a different stiffness; we have investigated the stability of the resulting microemulsion as well as resistance to biological defeat, protective and anti-corrosion properties in static and dynamic conditions, anti-foam properties at different temperatures. Industrial tests of emulsol pilot batch have been made in the Kemerovo region mines. In the process over a hundred recipes of Emulsol and 2% aqueous emulsions were prepared and tested.
KEYWORDS: cutting fluid, emulsol, emulsion, microemulsion.
STUDYING ANTIOXIDANT AND ANTIMICROBIAL PROPERTIES OF SULFUR-CONTAINING DERIVATIVES OF PARTIALLY HINDERED PHENOLS (P. 27-30)
Mamedova P.Sh., Dr. Sci. (Chem.), Prof., Head of laboratory «Additives to Cutting Fluids». E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Babayev E.R., Cand. Sci. (Chem.), Researcher. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Aеyvazova I.М., Cand. Sci. (Chem.), Leading Researcher. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript. , Institute of Chemistry of Additives after Academician A.M. Guliyev (Azerbaijan Republic, AZ1029, Baku, Beyukshor Highway, Block 2062).
Azizova S.M., Scientific Secretary, Ganja Branch of Azerbaijan National Academy of Sciences (ANAS) (Azerbaijan Republic, Ganja city, Heydar Aliyev Avenue, 153) E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Poletaeva O.Yu., Dr. Sci. (Tech.), Assoc. Prof.
Movsumzade E.M., Corresponding Member Russian Academy of education, Dr. Sci. (Chem.), Prof., Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Kolchina G.Yu., Cand. Sci. (Chem.), Assoc. Prof. of the Department of Chemistry and Chemical Technology, Federal State-Funded Educational Institution of Higher Professional Education Sterlitamak branch of Bashkir State University (47 a, Lenin St., 453103, Sterlitamak, Russia). Е-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The possibility of use of S-, Se-containing partially hindered bis-phenols as multifunctional (antioxidant, anticorrosive and antimicrobial) additives to lubricating oils has been studied.
KEYWORDS: partially hindered phenols, bis-phenols, oxidation inhibitors, antimicrobial additives.
RUSSIAN LOW-TONNAGE PRODUCTION FOR LIQUEFIED NATURAL GAS (P. 31-36)
Kondratenko A.D., student. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Karpov A.B., engineer of the Gaschemistry Department. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Kozlov A.М., Cand. Sci. (Tech.), Associate Prof. of the Refined Equipment Department. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Meshcherin I.V., Cand. Sci. (Tech.), Associate Prof. of the Gaschemistry Department. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript. , Gubkin Russian State University of Oil and Gas (65, korp.1, Leninskiy prosp., 119991, Moscow, Russia).
ABSTRACT
Low-tonnage production of liquefied natural gas occupies an increasingly significant place in the structure of LNG production. To date, in Russia a few small-capacity plants for the production of liquefied natural gas have been built and put into operation. Almost all the projects have been performed on various technologies that have their positive and negative aspects. This article provides an overview of technology solutions at available in Russia small-scale plants for liquefaction of natural gas.
KEYWORDS: liquefied natural gas, small-scale plant, LNG, gas fuel, gasification.
METHOD FOR PRODUCING ETHYLENE BY PYROLYSIS OF GASOLINE FRACTION OF HYDROCRACKING (P. 37-40)
Mnushkin I.A., Cand. Sci. (Tech.), General Director
Egutkin N.L., Dr. Sci. (Chem.), Prof., Senior Researcher, LLC «Research and Design Institute of Oil and Gas «PETON» (60/1, avenue Salavat Yulaev , Ufa, Republic of Bashkortostan, Russia).
ABSTRACT
The article describes a method of producing ethylene by pyrolysis of gasoline fraction of hydrocracking with initial boiling point of 35–40 °C and final boiling point not higher than 180 °C and containing of paraffinic hydrocarbons till C4 not less than 2%, paraffins C5–C10 about 50%, naphthenic hydrocarbon C5–C10 till 35%, aromatic hydrocarbons C9–C6 not more than 15%, including benzene not more than 2%, and olefinic hydrocarbon is not more than 1,0%. Pyrolysis is carried out in a reaction coil chamber tubular furnace radiation in the presence of steam at temperatures of 750–850 °C for 0,5–3,5 seconds at a ratio of steam: raw material in the range from 1: 1 to 3: 1. Technology of the process and examples of its
implementation are shown here.
KEYWORDS: ethylene, pyrolysis, gasoline fraction of hydrocracking,hydrocarbon feedstock, reactor.
STUDY OF ANTIOXIDANT PROPERTIES OF ARYLAMINE SUBSTITUTED THIIRANES (P. 41-44)
N.A. Akperov, Cand.Sci. (Chem.), Assoc. Prof., Azerbaijan State Pedagogical University (68, Hajibeyov St., AZ1000, Baku, Azerbaijan).
ABSTRACT
To search for more effective, multifunctional additives to petroleum prod-ucts and the determination of the interaction between the structure of the synthesized compounds and their antioxidant activity as lubricant additives antioxidant properties of arylamine thiiranes have been explored and studied in model reactions with cumyl peroxide radicals and cumyl hydroperoxide. Arylamine substituted thiiranes have been considered, which reacting with the peroxide radicals cut the chain of oxidation and the catalytically decompose cumyl hydroperoxide into molecular products. Arylamine substituted thiiranes are suggested to use as antioxidant additives to petroleum products.
KEYWORDS: petroleum products, lubricating oils, antioxidant additives, thiiranes.
COMPOSITE REAGENTS FOR THE DESTRUCTION OF COMPLEX OIL-WATER EMULSION OF THE OIL FIELDS IN WESTERN KAZAKHSTAN (P. 45-50)
Sarmurzina R.G., Dr. Sci. (Chem.), Prof., Acad. KazNANS
Karabalin U.S., Dr. Sci. (Tech.), Acad. NEARK
Akchulakov B.U., General Director, Association «Kazenergy» (19, Kabanbay batyr, 010000, Astana city, Republic of Kazakhstan). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Boyko G.I., Dr. Sci. (Chem.), Prof. of the Department of Chemical Engineering
Lubchenko N.P., Cand. Sci. (Chem.), Senior Researcher of the Department of Chemical Engineering
Panova Ye.S., Doctoral of the Department of Chemical Engineering, КаzNRTU named after K.I. Satpayev (22 B, Satpayeva, 050013, Almaty city, Republic of Kazakhstan). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The article presents the results of studies aimed at creating efficient composite demulsifier for breaking complex water-oil emulsions of highly viscous heavy oil, characterized by an abnormally high degree of aggregate stability. New nonionic composite demulsifiers KNTU-14,KNTU-16, KNTU-17 have been developed on the basis of industrial chemical Dissolvan 4795, Dissolvan 4908, Randem 2208 and ethoxylated polyols, POES-20, POES-80 and POES-85. The effectiveness of the new compositions of demulsifiers in comparison with industrially demulsifiers proven on the oils of Western Kazakhstan: Uzen and Karazhanbas, Bothan . The most effective for breaking emulsion are composite demulsifiers of KNTU-KNTU
14 and-16 brands.
KEYWORDS: oil, oil-water emulsions, demulsifiers, oil treatment.
A STUDY OF ENERGY EFFECT OF ELECTROMAGNETIC RADIATION OF MICROWAVE RANGE ON THE STRUCTURE AND PROPERTIES OF POLYMER INSULATING MATERIALS (P. 51-55)
Abutalipova E.M., Dr. Sci. (Tech.), Prof.
Pavlova I.V., Postgraduate student, Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Streltsov O.B., Senior Lecturer, Military Academy of the Strategic Missile Forces (8, Karbysheva St., 143900, Balashikha, Russia).
Gyul’maliev E.A., Postgraduate student, A.V. Topchiev., Institute of Petrochemical Synthesis RAS (TIPS RAS) (29, Leninskiy prosp., 119991, Moscow, Russia).
ABSTRACT
This article discusses an approach to improve technological and operational properties of polymeric insulating coatings of pipelines by their treatment by the electromagnetic field radiation of microwave range. In recent years, it has become quite widely used to find the electromagnetic radiation of a microwave (MW) range. Because it has several advantages: it intensifies the energy exchange in the matter by the converting of the radiated energy into the kinetic energy of molecular vibrations; provides a uniform treatment of the substance in the irradiated volume and high stability of the energy flow due to lack of persistence within the varying its power.
KEYWORDS: microwave radiation, the polymeric insulating coating, pipe, construction, method of calculation, the polymer, the electromagnetic field.
THE STUDY OF NATURAL GAS HYDRATES PROPERTIES OBTAINED FROM SOLUTIONS SIMULATING STRATAL WATER (P. 56-58)
Kalacheva L.P., Cand. Sci. (Chem.), Leading Researcher. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Fedorova A.F., Cand. Sci. (Tech.), Leading Researcher. E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript. , Institute of Oil and Gas Problems SB RAS (IPGP SB RAS) (1, Oktyabrskaya St., Yakutsk, 677891, Russia).
ABSTRACT
Experimental studies on the production and study of properties of natural gas hydrates of water and aqueous salt solutions have been carried out that simulate the composition of stratal waters. It is established that the properties of natural gas hydrates depend on the chemical composition of salt solutions and their concentration. The crystal morphology depends on the structure of salt crystals: a dense solid hydrate forms of the sodium chloride, and the hydrates of the layered structure form of solutions of calcium chloride.
KEYWORDS: natural gas hydrates, mineralization of solutions, the processes of formation and dissociation of hydrates.
GAS HYDRATES AS AN ALTERNATIVE SOURCE OF HYDROCARBONS (P. 59-61)
Obzhirov A.I., Dr. Sci. (Geol.-Min.), Prof., Head of the Laboratory of Gas and Geochemistry
V.I. Il ichev Pacific Oceanological Institute (43, Baltiyskaya St., Vladivostok, 690041, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The paper deals with the hydrocarbons that are under high pressure and with low temperature form gas hydrates. It is believed that gas hydrates contain around 10-100 billion m3 of methane in the sediments of the World ocean in the conditions of thermodynamic stability of preservation of gas hydrates. Gas hydrates can be considered as an alternative form of hydrocarbon deposits. We consider the conditions of formation of gas hydrates, sources of hydrocarbons, which form gas hydrates, the possibility of extracting methane of gas hydrates and their place in traditional and alternative sources of hydrocarbons. Understanding these processes helps to understand the sources of hydrocarbons, regularities of their formation, methods of exploration and extraction of hydrocarbons, which can be used as energy and chemical raw materials.
KEYWORDS: gas hydrates, an alternative source of hydrocarbons, the method of finding and extracting hydrocarbons.
KINETICS AND CATALYSIS
SPECIAL FEATURES OF PROPANE AROMATIZATION OVER Zr-ALUMINOSILICATE ZSM-5 CATALYSTS (P. 62-66)
Vosmerikova L.N., Cand. Sci. (Chem.), Senior Researcher
Volynkina A.N., Postgraduate student
Vosmerikov A.V., Dr. Sci. (Chem.), Head of the Laboratory, Institute of petroleum chemistry SB RAS (4, Akademichesky Avenue, 634055, Tomsk, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Zaikovskii V.I., Cand. Sci. (Chem.), Senior Researcher, Boreskov Institute of Catalysis SB RAS (5, Lavrentieva Avenue, 630090, Novosibirsk, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
A method of hydrothermal crystallization is used to manufacture zirconium aluminosilicate ZSM-5 zeolites from alkali alumosilicagels. Their physicochemical
and catalytic properties are investigated in the course of conversion of propane into aromatic hydrocarbons. The dependence of activity and selectivity of catalyst systems on concentration and electronic state of zirconium introduced into a zeolite is shown. The results of investigation allowed us to optimize a chemical composition of the catalyst, and to determine the optimal conditions for propane aromatization.
KEYWORDS: Zr-aluminosilicates, aromatization, propane, acidity, crystals, aggregates, clusters.
THE HISTORY OF SCIENCE AND TECHNOLOGY
CHARACTERISTICS OF SATURATED HYDROCARBONS ISOLATED FROM DIFFERENT TYPES OF HIGHER LAYERS OF NAFTALACHARACTERISTICS OF SATURATED HYDROCARBONS ISOLATED FROM DIFFERENT TYPES OF HIGHER LAYERS OF NAFTALAN OIL FIELD (P. 67-71)
Hashimova U.F., Dr. Sci. (Biol.), Director, Institute of Physiology named after A.I. Karaev, Azerbaijan National Academy of Sciences (ANAS) (78, Sharif-zadeh St., AZ1100, Baku, Azerbaijan)
Adigozalova V.A., Cand. Sci. (Biol.), Assoc. Prof., Department of Normal and Sport Physiology, Azerbaijan State Academy of Physical Culture and Sport (98, Fatali Khan Khoyski Avenue, AZ1072, Baku, Azerbaijan).
ABSTRACT
This paper discusses the study on physical and chemical properties and chemical composition of the oils from the various levels of the top part of Naftalan field to find the peculiarities of its biological effect. The following task was given: basis for the possible carrying out of medicine experimental tests of separate fractions of naphthenic hydrocarbons isolated from substandard Naftalan oil for the further exploitation of the latter. A difference in physical and chemical indeces of oils was found to be caused by the peculiarities of structure-group composition of saturated
components.
KEYWORDS: naftalan oil, physical, chemical properties, chemical composition, fractions.
The list of articles published in the journal "Oil & Gas Chemistry" in 2016 (P. 72-73)
Requirements to articles submitted for publication in the journal "Oil & Gas Chemistry" (P. 74)
Guidance on drafting annotation (P. 75)
