CONTENTS of journal "OIL & GAS CHEMISTRY" 1·2016 (Russia)
DAY OF RUSSIAN SCIENCE (P. 5)
NEWS (P. 6-7)
GAS SULPHR: PROBLEMS AND SOLUTIONS
THE FEASIBILITY OF CREATION OF THE NEW SUB-SECTOR IN INDUSTRY – THE SULPHUR CONSTRUCTIVE (P. 8-13)
Motin N.V., Cand. Sci. (Tech.), Head of the Laboratory Gazprom VNIIGAZ (pos. Razvilka, Leninsky district, Moscow Region, 142717, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Vasil’ev Yu.E., Cand. Sci. (Tech.), Head of the Laboratory Moscow Automobile and Road Construction University (MADI). (64, Leningradskiy prosp., 125319, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Shubin A.N., Director OOO NPP «Prospectus» (16, Sadovaya-Triumfalnaya str., 127006 Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Alekchina M.N., Cand. Sci. (Tech.), Deputy head of the Laboratory E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Tkachov V.P., Engineer Gazprom VNIIGAZ (pos. Razvilka, Leninsky district, Moscow Region, 142717, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The article describes the new road-building materials based on sulfur – sulphur-asphultconcrete and sulfur concrete. Positive properties and novelty allows to call them innovation and create a new sub-industry production of building sulfur composites.
Keywords: sulphur-asphult mixtures, sulphur-asphultconcrete, sulphur-concrete, road-building materials, sulphur.
CHEMICAL TECHNOLOGIES AND PRODUCTS
EVALUATION OF EFFECTIVENESS PROCESS OF STEAM CRACKING WITH GTL-NAPHTHA (P. 14-18)
Karpov A.B., Postgraduate student of the Gaschemistry Department
Mescherin I.V., Cand. Sci. (Tech.), Associate Prof. of the Gaschemistry Department
Lapidus A.L., Corresponding Member RAS, Dr. Sci. (Chem.), Prof. of the Gaschemistry Department
Zhagfarov F.G., Dr. Sci. (Tech.), Prof. of the Gaschemistry Department
Kondratenko A.D., Bachelor Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy pr., 119991, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The article deals with indirect processes for producing lower olefins from natural gas. One such technology, which combines the Fischer-Tropsch (GTL) process with a traditional steam cracking. Presents the advantages and disadvantages of the use of synthetic naphtha in the process of steam cracking. It is shown that in the pyrolysis of synthetic gasoline fractions observed increased yields of lower olefins and reduced coking. In the simulation, it is determined that the feasibility of producing light olefins from natural gas by a combination of GTL plants and steam cracking has been at oil prices of more than US $ 60 / barrel. The overall economic efficiency while significantly exceeds the effect of the traditional options for the production of lower olefins. Proposed by high oil prices and, consequently, to the naphtha used to produce lower olefins combined technology of Fischer-Tropsch synthesis and steam cracking.
Keywords: steam cracking, synthetic liquid hydrocarbons, assessment of efficiency, coke formation, lower olefins.
SPECIAL FEATURES OF PROPANE AROMATIZATION OVER GA-CONTAINING ZEOLITES PREPARED BY DIFFERENT METHODS (P. 19-23)
Vosmerikova L.N., Cand. Sci. (Chem.), Senior Researcher
Volynkina A.N., Postgraduate
Vosmerikov A.V., Dr. Sci. (Chem.), Head of the Laboratory Institute of petroleum chemistry SB RAS (4, Akademichesky prosp., 634055, Tomsk, Russia)
Zaikovskii V.I., Cand. Sci. (Chem.), Senior Researcher Boreskov Institute of Catalysis SB RAS (pr. Lavrentieva 5, Novosibirsk, 630090, Russia)
ABSTRACT
Acidic and catalytic properties of gallium-containing zeolites of ZSM-5 structure type prepared by different methods in the course of conversion of propane into aromatics are investigated. The dependence of activity and selectivity of catalyst systems on localization and electronic state of gallium introduced into a zeolite and acid characteristics of the zeolite itself is shown. It is found out that most of aromatic hydrocarbons are formed during the conversion of propane on the zeolite catalyst, which contains gallium introduced by impregnation.
Keywords: Ga-containing zeolites, aggregates, acidity, propane, aromatic hydrocarbons.
A STUDY OF SATURATED HYDROCARBONS AND OPPORTUNITIES
OF THEIR USAGE (P. 24-27)
Adigozalova V.A., Cand. Sci. (Biol.), Associate Prof., Department of Normal Physiology Azerbaijan State Academy of Physical Culture and Sport. (98, Fatali Khan Khoyski ave., AZ1072, Baku, Azerbaijan)
ABSTRACT
This paper discusses study on physical and chemical properties and chemical composition of oils of Naftalan field to find the peculiarities of its biological effect. A comparative study on structure-group composition of saturated hydrocarbons isolated from differed by the properties samples of Natalan oil was done to find their «working start».
Keywords: naftalan oil, physical and chemical characteristics, biological activity.
ECOSYSTEM PROTECTION AND UTILIZATION OF INDUSTRIAL WASTES
ON ELIMINATION OF PAST ENVIRONMENTAL LIABILITIES (P. 28-33)
Soloviyanov A. Alexander, Dr. Sci. (Chem.), Full. Prof., Academician of the Russian Academy of Natural Sciencies, Deputy Director Research Institute of Environmental Protection (Institute of Ecology). (Estate «Znamenskoye Sadki», 117628, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The process of development and results of the Russian legislature on elimination of past environmental liabilitieswere described. The Governmental Decree on December 4 of 2014 N 2462-p «On approval of the most important measures devoted to elimination of impact of pollution and other types of negative events on environment as a result of economic and other activities» was described.
Keywords: past environmental liabilities, projects of the Russian laws on elimination of past environmental liabilities, the Governmental Decree on December 4 of 2014 N2462-p
KINETICS AND CATALYSIS
ABOUT DYNAMIC COMPENSATION EFFECT IN THE CATALYSIS (P. 34-39)
Tretyakov V.F., Dr.Sci. (Chem.), Prof., Chief Researcher
Ilolov A.M., Cand. Sci. (Chem.), Researcher
Talyshinsky R.M., Dr.Sci. (Chem.), Leading Researcher Gyul’maliev E.A., Post-graduate student A.V. Topchiev Institutof Petrochemical Synthesis (TIPS RAS) (29, Leninskiy prosp., 119991, Moscow, Russia)
ABSTRACT
More general is received in comparison with the kinetic compensation effect (KCE) mathematical expression of the dynamic compensation effect (DCE) in a catalysis. Classification of processes by a scale is offered: a catalysis, initiation, induction depending on number of the mobile active centers which are formed under the influence of interaction of the inductor (or the initiator) catalytic process. The numerical analysis of decrease in an activation barrier at simultaneous increase in number of active impacts is carried out. The concept catalytic system which, along with the catalyst and the reactionary environment, the initiator or the inductor includes is expanded.
Keywords: initiation, induction, catalyst, resonance, catalytic system, reactionary environment.
ABOUT DESTRUCTION OF METHANATION CATALYST UNDER THE ACTION OF POTASSIUM CARBONATE WATER SOLUTION OF POTASH II. NICKELIFEROUS CEMENTCONTAINING CATALYST OF NIAP-07-07 (NKM-7) (P. 40-44)
Efremov V.N., Cand. Sci. (Tech.), Chief Researcher
Kashinskaya A.V., Engineer
Polivanov B.I., Head of a Department
Golosman E.Z., Dr. Sci. (Chem.), Chief Researcher Novomoskovsk Institute of the Nitrogen Industry (LLC «NIAP-KATALIZATOR») (10, Svyazy st., Novomoskovsk, 301660,Tula Region, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Polushin A.P., Production Director JSC «Novomoskovskaya joint stock company «NITROGEN» (10, Svyazy st., Novomoskovsk, 301660, Tula Region, Russia).
ABSTRACT
Results over are brought of researches of influence of water solution of potash, being the absorbent of dioxide of carbon, on physical and chemical and physical-mechanical descriptions of nickeliferous cementcontaining catalyst of NIAP-07-07 (NKM-7) hydrogenizing of oxides of carbon (metahanation). It is set that the created new nickeliferous catalyst in that the aluminate of calcium executes the role of hydraulic connective shows high stability at affecting him water solution of potash. The catalyst of NIAP-07-07 (NKM-7) restores the properties after washing of layer of catalyst by a hot runback or after his blowing out moist saturated.
Keywords: nickeliferous catalyst, aluminate of calcium, metahanation, activity, hydrogenizing, oxides of carbon, solution, potash, decontamination, durability.
NANODIMENSIONAL DYNAMIC COMPENSATION EFFECT IN THE INITIATED HETEROGENEOUS AND CATALYTIC PROCESS (P. 45-50)
Talyshinsky R.M., Dr.Sci. (Chem.), Leading Researcher
Gyulmaliyev E.A., Postgraduate student
Tretyakov V.F., Dr.Sci. (Chem.), Prof., Chief Researcher
Ilolov A.M., Cand. Sci. (Chem.), Researcher A.V. Topchiev Institut of Petrochemical Synthesis (TIPS RAS) (29, Leninskiy prosp., 119991, Moscow, Russia)
Litvishkov Yu.N., Dr.Sci. (Chem.), Prof., Corresponding Member NAS of Azerbaijan
Muradova P.A., Cand. Sci. (Chem.), Senior Researcher Institute of Catalysis and Inorganic Chemistry of the National Academy of Sciences of Azerbaijan (29, ave.HuseynJavid, AZ 1143, Baku,Azerbaijan).
Kotelev M.S., Cand. Sci. (Chem.), Senior Researcher Gubkin Russian State University of Oil and Gas (National Research University). (65, korp.1, Leninskiy pr., 119991, Moscow, Russia).
Movsumzade E.M., Corresponding Member Russian Academy of education, Dr. Sci. (Chem.), Prof. Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
Basic possibility of regulation of nanodimension of the formed zinc oxide microcrystallites on a surface of ZnO/γAl2O3/Al of the catalyst of the initiated transformation of ethanol into divinyl with participation of hydrogen peroxide at influence of the microwave oven of radiation in the course of its preparation is established. By means of IR spectroscopic analysis, the scanning electronic microscopy (SEM), kinetic researches of process with attraction of quantum and chemical calculations dependence of character of a hydroxylation of a surface of ZnO/γAl2O3/Al of the catalyst, and also nanodimension of structural fragments of its active weight on concentration of hydrogen peroxide and parameters of influence of the microwave oven of radiation is established. It is shown that the dynamic compensation effect observed at an assessment of power parameters
of the reaction stimulated by microwave radiation is caused by formation of high-disperse nanodimensional structure of the superficial centers coordinating hydroxyl groups the showing optimum acid properties.
Keywords: heterogeneous catalysis, dynamic compensation effect, nanodimension, initiator, hydrogen peroxide, microwave oven radiation.
THE HISTORY OF SCIENCE AND TECHNOLOGY
OVERVIEW OF THE MAIN ACHIEVEMENTS OF MANKIND IN QUANTUM CHEMISTRY (P. 51-60)
Kolchina G.Yu., Cand. Sci. (Chem.), Assoc. Prof. of the Department of Chemistry and Chemical Technology
Federal State-Funded Educational Institution of Higher Professional Education Sterlitamak branch of Bashkir State University (47 a, Lenin St., 453103, Sterlitamak, Russia). Е-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Movsum-zade N.Ch., Cand. Sci. (Tech.), Researcher Institute of information technology of NAS of Azerbaijan (9, B. Vahabzade, Baku, Azerbaijan Republic, AZ1141).
Bakhtina A.Yu., Postgraduate of the Department of General and Analytical Chemistry
Movsumzade E.M., Corresponding Member Russian Academy of education, Dr. Sci. (Chem.), Prof. Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
The article gives a brief account of the history and basics of classical and quantum chemistry. Brief description of the quantum programs.
Keywords: quantum chemistry, the Schаdinger equation, the Hartree-Fock method, quantum chemical program, GAMESS, GAUSSIAN, scientistschemists.
EVALUATION OF HYDROCARBON RESOURCES
THE DISTRIBUTION OF METALS IN THE OIL SOUTH - EASTERN PART OF THE ORENBURG AREA (P. 61-63)
Zakharchenko M.V., Post-graduate of the Theoretical Basics of Prospecting and Exploration of Oil and Gas Department Lyushinm M.M., Dr. Sc. (Chem.), Head of the Laboratory geochemical of the Theoretical Basics of Prospecting and Exploration of Oil and Gas Department Gubkin Russian State University of Oil and Gas (National Research University) (65, korp.1, Leninskiy pr., 119991, Moscow, Russia). E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Mustafina E.A., Post-graduate student at the department of General and analytical chemistry Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia).
ABSTRACT
The results of the study of metals in the oil from the south - eastern part of the Orenburg region. The peculiarities of their distribution in relation to the physical-chemical properties of oil fields: Orenburg, Kopanskoe, Tsarichanskoye.
Keywords: metal, especially the distribution of physical and chemical properties of oil, stratigraphic correlation.
JUBILEE DATES
Academician N.D. Zelinsky / Russian creator of school of organic chemists, the founder of the doctrine about organic heterogeneous catalysis (P. 64-68)
The Institute of neftekhimpererabotki of the Republic of Bashkortostan – 60 years (P. 69-72)
