CONTENTS of journal "OIL & GAS CHEMISTRY" 4·2015 (Russia)

JUBILEE DATES

Original Scientist 3 Research Scientist 3 Organizer  (P. 6-8)
Creator of control and information systems  (P. 9-11)

DEVELOPMENT STRATEGY

PROSPECTS OF DEVELOPMENT OF GAS ANDPETROCHEMICAL COMPLEX OF THE REPUBLIC OF TATARSTAN (P. 12-16)
Yarullin R.S., Dr. Sci. (Chem.), Prof., General Director Tatneftekhiminvest-holding (29A, Yershov st., Kazan, 420061, Republic of Tatarstan, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра. .
ABSTRACT
The realization a fourth Program of development of gas and petrochemical complex has been started in the Republic of Tatarstanfrom 2015 to 2019. The articlerevealed the goals and objectives of the Program, described the main projects and expected status of the complex in 2019.
KEYWORDS: Republic of  Tatarstan, petrochemical complex, oil production, petroleum chemistry, petroleum refining, cluster.

CHEMICAL TECHNOLOGIES AND PRODUCTS

THE SECOND STEP OF REFINERING OF PETROLEUM CRAFT GAS UP TO GET CHEMISTRY COMPOUNDS (P. 17-21)
Vertyagin S.A., researcher
Borodin A.V., Cand. Sci. (Tech.)
Movsumzade E.M., Corresponding Member Russian Academy of education, Dr. Sci. (Chem.), Prof. Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
In the last year the problem of utilization the fair petroleum gas in Russia was the essential and bread discussion. The state company are struggle for an expedient cremation the fair petroleum gas, so as this gas, was accessory product of extraction petroleum. Usually the change system and size payment of more than norm of cremation PCG (petroleum craft gas). Petroleum company to strive for increase up till 95% quantity utilization PCG. All this factors own favourable to influence on increase supply fair petroleum gas on gasrefinering industry and further use as a raw material for petrochemistry industry.
In whole Russia in 2013 year production fair petroleum gas increase on 4% up to 73,229 billion m3, compared with analogous previous period, but supply PCG on refinering on total 2 quarter 2013 year increase on 3% or 249 million m3.
The essential volume extraction to come on Ural Federal district. Majority subjects UFD to passes larger field mineral material. In Hanty-Mansiyskom and Yamalo-Neneckom antonomy district exploration and to exploit petroleum and gas field, consist West-Siberya petrogas province, where to concentrate 66,7% supply petroleum Russia (6% – of the world) and 77,8% of the gas Russia (26% of the world supply).
KEYWORDS: petroleum craft gas; natural gas; main steps of refinering gas; wide fraction of light hydrocarbons; liquefied petroleum gas.

THE PRODUCTION OF POLYMER COMPOSITES AND INFLUENCE OF PRODUCTION FACTORS ON THE RESULTING PROPERTIES OF COMPOSITE PARTICLES (P. 22-27)
E. Stranska, M.Sc.
D. Nedela, M.Sc.
J. Krivcik, M.Sc.
K. Weinertova, M.Sc. MemBrain (Czech Republik, Straz pod Ralskem 471 27, Pod Vinici 87, www.membrain.cz ), Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра., phone: +420 725 358 422
ABSTRACT
The goal of this work is discussion of the effect of production on the properties of the particle composite. As the partzicel filler are used hydrophilic particles than they are participated in electrochemical properties. The reinforcing fabric is used as the further element, which determines mechanical and physical properties. The particles is milled to the desired particle size distribution in the first step and compounded with the polymeric matrix. Composite mixture is moulded with the reinforcing fabric to the desired shape. Individual components are characterized and their effect on the final properties of particle composite is determined.
KEYWORDS: preparation of polymer composite, grinding of filler, laboratory control.

MEMBRANE INNOVATION CENTRE (MIC) (P. 28-30)
Morozova Ya., M.Sc. MemBrain (Czech Republik, Straz pod Ralskem 471 27, Pod Vinici 87, www.membrain.cz )
 
THE DEFINITION OF ENERGY IS AN IMPORTANT FACTOR IN THE IMPLEMENTATION OF NATURAL GAS (P. 31-34)
Kozlov A.M., Cand. Sci. (Tech.), Assistant chair of the Gaschemistry Department
Karpov A.B., Postgraduate student of  the Gaschemistry Department
Fedorova E.B., Cand. Sci. (Tech.), Associate Prof., Deputy Head of Processing Equipment Chair
Zhagfarov F.G., Dr. Sci. (Tech.), Prof. of the Gaschemistry Department Gubkin Russian State University of Oil and Gas (Leninskiy prosp., 65, korp.1, 119991, Moscow, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
The increased cost of energy and the appearance of different gas qualities led to the fact that the calculations in the gas industry started to produce thermal energy by measuring, in turn, need to determine the heat of combustion from measurements or calculations led to a number of methods of determining appropriate. However, the procedure by which the calorific value brought into correspondence with the data on the volumetric flow rate to determine the energy content in a given volume of natural gas is not sufficiently standardized.
Determination of energy, usually a prerequisite, whatever the time and location of the measurement parameters of the natural gas from mining operations and processing until the gas consumption by the end user. To solve the problems associated with the production, transport and distribution of gas to the end consumer remains urgent issue of developing a standardized methodology for measuring energy of natural gas.
KEYWORDS: energy, natural gas, measurement methods, heat of combustion, quality

DETERMINATION OF INORGANIC IMPURITIES BY ISP - MS IN TRIETHYLENE GLYCOL AFTER DRYING OF NATURAL GAS (P. 35-39)
Usachev M.N., Cand. Sci. (Chem.), graduate student of the Department of Analytical Chemistry
Efimova Yu.A., Dr. Sci. (Chem.), Assoc. Prof. of the Department of Analytical Chemistry
Zaitsev N.K., Dr. Sci. (Chem.), Assoc. Prof. of the Department of Analytical Chemistry Lomonosov Moscow State University of  Fine  Chemical Technologies (86, pr. Vernadsky, 119571, Moscow, Russia)
ABSTRACT
The absorption drying process of the natural gas in the adsorbent leads to accumulation of inorganic impurities. This study resulted in a method for their ICP-MS determination in triethylene glycol. Possible sources of adsorbent pollution were accounted for.
KEYWORDS: absorption drying of natural gas; mass spectrometry with inductively coupled plasma; determination of impurities in triethylene glycol.

GEOCHEMICAL CHARACTERISTICS OF OILS ORENBURG REGION OF HYDROCARBON BIOMARKERS (P. 40-44)
Zakharchenko M.V., engineer of the Theoretical Basics of Prospecting and Exploration of Oil and Gas Department
Lyushinm M.M., Dr. Sc. (Chem.), Head of  the Laboratory geochemical of the Theoretical Basics of Prospecting and Exploration of Oil and Gas Department
Osipov A.V., Cand. Sci. (ph.d.) assoc. prof. of the Theoretical Basics of Prospecting and Exploration of Oil and Gas Department Gubkin Russian State University of Oil and Gas (65, korp.1, Leninskiy prosp., 119991, Moscow, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
Using the technique of capillary gas-liquid chromatography and hromato-mass-spectrometry the geochemical estimation of hydrocarbon biomarkers samples of three oil fields of the Orenburg region Orenburgskoe, KopanskoeTsarichanskoye isproduced. The results of the distribution in oils n-alkanes, isoprenanes, steranes and terpanes, as well as their interpretationare presented.
KEYWORDS: oil Orenburg region, gas-liquid chromatography, hromatomass- spectrometry,n-alkanes, izoprenany, steranes.

DEHYDROGENATION WITH INTERMEDIATE OXIDATION FORMED HYDROGEN (P. 45-48)
Karimov E.Kh., Cand. Sci. (Tech.), Head Group of Catalytic Processes JSC «Sterlitamak petrochemical plant» (14, Technical str., 453100, Sterlitamak, Russia).
Karimov O.Kh., Ph.D., Assoc. Prof. of General Chemical Technology Branch Ufa State Petroleum Technological University (USPTU) (2, Pr. Oktyabrya, 453118, Sterlitamak, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
The paper shows the possibility of combining the endothermic dehydrogenation oxidation processes in order to compensate heat losses. On the example of the dehydrogenation isoamylenes in isoprene conducted laboratory tests interlayer catalytic oxidation of hydrogen produced. In discussing the results, we consider the hypothesis of the presence of the oxidation zone of short-term oxidative dehydrogenation of isoamylenes.
KEYWORDS: dehydrogenation, iron oxide, isoprene, isoamylene, the oxidation of hydrogen.

PROTECTION OF ECOSYSTEMS AND UTILIZATION OF INDUSTRIAL WASTES

BIOLOGICAL UTILIZATION OF HEAVY METALS (P. 49-51)
Babayev E. R., Dr. Sci. (Chem.),
Farzaliyev V.M. Active Member of Azerbaijan National Academy of Sciences, Dr. Sci. (Chem.), Prof.
Mamedova. P.Sh. Dr. Sci. (Chem.), Prof. Institute of Chemistry of Additives after Academician A.M. Guliyev (Azerbaijan Republic, AZ1029, Baku, Beyukshor Highway, Block 2062 ) Email: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
Movsumzadeh E.M., Corresponding Member Russian Academy of education, Dr. Sci. (Chem.), Prof. Ufa State Petroleum Technological University (USPTU) (1, Kosmonavtov St., 450062, Ufa, Russia) E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
A  problem of pollution of the main components of environment  with oil products  being accompanied  by such pollutants as polycyclic aromatic hydrocarbons and heavy metals is one of  the principal  tasks of applied ecology. There has been described  a scheme of phytoextraction of heavy metals from contaminated soils of Absheron Peninsula. Selection of wild plants which are resistant to oil and can accumulate a wide range of metals has been realized. The paper also presents data on the study of microbial community of root zone of plants.
KEYWORDS: phytoremediation, heavy metals, microbal community, degradation of oil hydrocarbons.

KINETICS AND CATALYSIS

ACIDIC SURFACE PROPERTIES OF ALUMINA-REINFORCED ALUMINUM CARRIERS GENERATED IN THE MICROWAVE (P. 52-55)
Muradova P.A., Cand. Sci. (Chem.), Senior Researcher
Zulfugarova S.M. Cand. Sci. (Chem.), Senior Researcher
Shakunova N.V. Cand. Sci. (Chem.), Senior Researcher
Litvishkov Yu.N., Dr.Sci. (Chem.), Prof., Corresponding Member NAS of Azerbaijan Institute of Catalysis and Inorganic Chemistry of the National Academy of Sciences of Azerbaijan (29, ave.HuseynJavid, AZ 1143, Baku,Azerbaijan).E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
Тretyakov V.F., Dr.Sci. (Tech.), Prof.
Talyshinskiy R.M., Dr.Sci. (Chem.), Chief Researcher A.V. TopchievInstitutof Petrochemical Synthesis (TIPS RAS) (29, Leninskiy prosp., 119991, Moscow, Russia).
ABSTRACT
This paper presents results of acid properties study of the synthesized under the effect of the microwave field samples A12O3 / A1 support active mass potential catalysts caused by the temperature-programmed desorption (TPD)  with ammonia method. It identified uniformly heterogeneous nature of the distribution group of acid sites on the strength of binding of ammonia, which corresponds to a logarithmic adsorption isotherm within the boundaries on the respective groups of centers. Calculated energy resource parameters desorption of ammonia from the surface of A12O3 /A1-carriers formed in the conventional heat treatment conditions (electrical heating) and heat treatment in the microwave field, whereby the surface acid sites are ranked as «weak», «moderate» and «severe».
KEYWORDS: acidity, temperature-programmed desorption, ammonia, electromagnetic radiation, microwave, А12О3/Аl.

COUPLING AND INITIATION OF CHEMICAL REACTIONS IN HETEROGENEOUS CATALYSIS (P. 56-61)
Ilolov A.M., Cand. Sci. (Chem.), Researcher
Budnyak A.D., Junior Researcher A.V. Topchiev Institut of  Petrochemical Synthesis (TIPS RAS) (29, Leninskiy prosp., 119991, Moscow, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
Ezinkwo G.O., Bachelor Lomonosov  Moscow State University of  Fine Chemical Technologies (86, Vernadskogo prosp., 119571, Moscow, Russia).
ABSTRACT
Effect of inducing (initiator - hydrogen peroxide) in the conversion of lower alcohols in heterogeneous catalytic reactions is investigated. Count the thermodynamics and kinetics of the process. The basic functions of action initiator under the reaction conditions are determined. Showing new prospects for the use of hydrogen peroxide in heterogeneous catalysis.
KEYWORDS: catalysis, induction, methanol, ethanol, formaldehyde, divinyl.

ABOUT DESTRUCTION OF METHANATION CATALYST UNDER THE ACTION OF POTASSIUM CARBONATE WATER SOLUTION OF POTASH. I. THE NICKEL-ALUMINIUM CATALYST NIAP- 07-01 (NKM- 1) (P. 62-66)
Efremov V.N., Cand. Sci. (Tech.), Chief  Researcher
Kashinskaya A.V., Engineer
Polivanov B.I.,  Head of a Department
Boevskaya E.A., Leading Researcher
Golosman E.Z., Dr. Sci. (Chem.), Chief  Researcher Novomoskovsk Institute of the Nitrogen Industry (LLC «NIAP-KATALIZATOR») (10, Svyazy st., Novomoskovsk, 301660,Tula Region, Russia). E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
The results of studies on the action of the potassium carbonate aqueous solution, used as the absorbent of carbon monoxide, on the physical, chemical and mechanical characteristics of the nickel-aluminum catalyst NIAP-07-01 (CCM-1) for hydrogenation of carbon oxides (methanation) are presented. It is found that the result of this action is the formation of potassium carboaluminate responsible for the destruction of the catalyst. It is shown that the washing with the hot condensate of the catalyst treated with potassium carbonate, or its blowdown with the wet saturated vapor, does not lead to the restoration of its properties. It was found that the best option is to upload the frontal layer of spent catalyst under the atmosphere of nitrogen.
KEYWORDS: nickeliferous catalyst, metahanation, hydrogenizing, oxides of carbon, solution, potash, decontamination, durability.

Information FAST ENGINEERING (P. 67)

List of articles published in 2015 (P. 68-69)

PATENT INFORMATION SURVE (P. 70-71)

 

 

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