CONTENTS of journal "OIL & GAS CHEMISTRY" 3·2014 (Russia)

REFINERY DIRECTIONS OF DIFFERENT TYPES OF RAW MATERIALS (OIL, GAS, OIL SHALE AND COAL) FOR THE HYDROCARBONS PRODUCTION

Poletaeva O.Yu., Cand.Tech.Sci., Ufa State Petroleum Technological University (1, Kosmonavtov ul., Ufa, 450062, Russian Federation)
Latypova D. Zh., Lecturer, Cand.Tech.Sci., Ufa State Petroleum Technological University (1, Kosmonavtov ul., Ufa, 450062, Russian Federation)
Mukhametzyanov I.Z., Graduate Student, Ufa State Petroleum Technological University (1, Kosmonavtov ul., Ufa, 450062, Russian Federation)
Karimov E.H., Cand.Tech.Sci., Specialist laboratory catalysis, Sterlitamak Petrochemical Plant (14, ul. Technicheskaya, Sterlitamak, Republic of Bashkortostan, 453110, Russian Federation)
Movsumzade E.M., Prof., Ufa State Petroleum Technological University (1, Kosmonavtov str., Ufa, 450062, Russian Federation)
Borodin A.V., Cand.Tech.Sci., Gazprom Neft (3-5, ul. Pochtamtskaya, Saint-Petersburg, 190000, Russian Federation)
ABSTRACT
The paper presents the main areas of hydrocarbons production. Technological schemes of oil associated gas turning, and the diagram of the steps of oil in commercial gas main fractions transformation: dry stripped gas, a broad fraction of light hydrocarbons and stable natural gasoline.
An important alternative method for hydrocarbons processing is the interaction of carbon monoxide and hydrogen. Analyzed catalytic methods for producing synthesis gas (carbon monoxide and hydrogen), and turning them into hydrocarbons. Also examined the gasification reaction shale, coal, heavy oil and oil products recycling. Experimentally presented thermal gasification oxygen, secondary petrochemicals at high temperature to form gaseous and liquid hydrocarbons.
Keywords: oil trade gas, refining, coke, coal, shale, crumb rubber.

STUDY OF STRUCTURE ETHYLENE OLIGOMERS ON THE SYNTHESIS OF ALKENYL SUCCINIC ANHYDRIDE

Kuzmenko M.F. Institut neftekhimpererabotki Respubliki Bashkortostan (12, Intsiativnaya ul., Ufa, Bashkortostan, 450065, Russian Federation)
Shiriyazdanov R.R. Institut neftekhimpererabotki Respubliki Bashkortostan (12, Intsiativnaya ul., Ufa, Bashkortostan, 450065, Russian Federation)
Davletshina A.R. Institut neftekhimpererabotki Respubliki Bashkortostan (12, Intsiativnaya ul., Ufa, Bashkortostan, 450065, Russian Federation)
Liakumovich A.G. Kazan State Technological University (68, ul. Karl Marx, Kazan, 420015, Russian Federation)
Hayrudinov I.R. Institut neftekhimpererabotki Respubliki Bashkortostan (12, Intsiativnaya ul., Ufa, Bashkortostan, 450065, Russian Federation)
Telyashev E.G. Institut neftekhimpererabotki Respubliki Bashkortostan (12, Intsiativnaya ul., Ufa, Bashkortostan, 450065, Russian Federation)
Rakhimov M.N. Ufa State Petroleum Technological University (1, Kosmonavtov str., Ufa, 450062, Russian Federation)
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ABSTRACT
The results of research synthesis effective succinimide additive that gives the engine oil and fuel detergent and dispersant properties. To study the course of the synthesis of alkenyl succinimides were investigated by NMR spectroscopy of ethylene oligomers of different structures with an average molecular weight of 300-700, is an intermediate product.
According to the study, it was decided to use synthesis alkenylsuccinic anhydride ethylene oligomers containing mainly dialkyl alphaolefins. Also found that alpha-olefins monoalkilzameschennyh oligomers can be used as an additional component in the production of raw succinimides, but under certain conditions and adjustment of operating parameters of the synthesis of alkenyl succinic anhydride.
Preliminary results of many experiments show that the use of structured oligomers of different origin under certain conditions of synthesis and greatly enhances the protective effects of dispersion succinimides.
Keywords: succinimide additive synthesis, the oligomers of ethylene, alkenylsuccinic anhydride.

DEVELOPMENT CYCLOHEXANOL DEHYDROGENATION CATALYSTS FOR THE PRODUCTION OF CAPROLACTAM

Vanchurin V.I., D. Mendeleyev University of Chemical Technology (9, Miusskaya Sq., Moscow, 125047, Russia) E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
Pavlov Yu.L., D. Mendeleyev University of Chemical Technology (9, Miusskaya Sq., Moscow, 125047, Russia)
Dzhumamuhamedov D.Sh., D. Mendeleyev University of Chemical Technology (9, Miusskaya Sq., Moscow, 125047, Russia)
Marachuk L.I., Grodno Azot (100, ul. Cosmonauts, Grodno, 230013, Belarus)
Dulnev A.V. , NIAP catalyst (10, ul. Svyazi, Novomoskovsk, Tula region, 301660, Russia)
ABSTRACT
Developed new copper-aluminum-silicon catalyst MAK-K for dehydrogenation process using ammonium carbonate technology. Selectivity of the catalyst is at the level of selectivity of best foreign analog H3-11 developed by BASF, wherein its activity and thermostability significantly higher. Technology of catalyst MAK-K mastered in pilot-production shop of NIAP-KATALIZATOR LLC.
Keywords: copper-containing catalysts, dehydrogenation of cyclohexanol, thermostability, activity, selectivity.

INVESTIGATION OF THE DYNAMICS OF TRANSFORMATION TO ETHANOL IN DIVINYL WITH INDUSTRIAL CATALYSTS K-64

Tretyakov V.F., Dr. Chem. Sci., Prof., A.V.Topchiev Institute of Petrochemical Synthesis, RAS (29, Leninsky prosp., Moscow, 119991, Russian Federation)
Ilolov A.M., Cand. Chem. Sci., A.V.Topchiev Institute of Petrochemical Synthesis, RAS (29, Leninsky prosp., Moscow, 119991, Russian Federation)
Ezinkvo G.O., Graduate student, Lomonosov Moscow State University of Fine Chemical Technology (86, Vernadsky prosp., Moscow, 119571, Russian Federation)
Zaboristov V.N., Dr. Tech. Sci., Efremov Synthetic Rubber Plant (2, ul. Stroiteley, Efremov, Tula region, 301840, Russian Federation)
Slizov A.A., Head of Technical Department, Efremov Synthetic Rubber Plant (2, ul. Stroiteley, Efremov, Tula region, 301840, Russian Federation)
Ryakhovskiy V.S., Chief Engineer, Efremov Synthetic Rubber Plant (2, ul. Stroiteley, Efremov, Tula region, 301840, Russian Federation)
Talyshinskiy R.M., Doctor of Chem. Sci., Prof., A.V.Topchiev Institute of Petrochemical Synthesis, RAS (29, Leninsky Prospect, Moscow, 119991, Russian Federation)
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ABSTRACT
The principal possibility of initiating an industrial process of transformation of ethanol in divinyl hydrogen peroxide on magnesium-silicon catalyst K-64. Demonstrated the effect of hydrogen peroxide on the burning of coke and suppression of ethylene in the dynamic impact of the initiator.
On the basis of spectral data suggested theoretical hypothesis that magnesium oxide suppresses the formation of ethylene in the fresh and partially coked catalyst. At the same time there is some optimal degree of coking surface corresponding to the stretching of magnesium oxide MgO, which inhibits the formation of ethylene.
Keywords: ethanol, butadiene, catalysis, magnesium-silicon catalyst K-64, hydrogen peroxide.

ANALYSIS OF TNE MAIN POLYMERIC MATERIAL’S NORMATIVE DOCUMENTS FOR GAS IPELINES

Zubairov Т.A., Graduate Student, Mastobaev B.N., Doctor of Tech. Sci., Professor, E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
Fattakhov М.М., Doctor of Tech. Sci., Associate Professor
Ufa State Petroleum Technological University (1, Kosmonavtov str., Ufa, 450062, Russian Federation)
ABSTRACT
This article includes the materials of the analysis of the main Russian and foreign polymeric material’s normative documents, applied for gas pipelines. Information about the materials for polyethylene pipes and connecting details’ production, requirements, information about the factories, the main provisions for the construction and operation of gas pipelines is given.
Keywords: normative documents, gas pipeline, polyethylene, polymeric materials.

15TH ANNIVERSARY OF THE DEPARTMENT GASCHEMISTRY OF GUBKIN RUSSIAN STATE UNIVERSITY OF OIL AND GAS

ABSTRACT
His fifteen-year anniversary celebrated department gaschemistry of Gubkin Russian State University of Oil and Gas, led by professor, corresponding member of the Russian Academy of Sciences A.L.Lapidus. Summarizes the work done during this time teaching and research work. The history of the creation of the department. The experience of the educational process at the department, advances in scientific work.
Keywords: gas chemistry, Department, Gubkin Russian State University of Oil and Gas.

 

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