Oil fishery-gas and ways him conversion
Aleksandrova A.Yu., Ufa State Petroleum Techological University (1, Kosmonavtov str., Ufa, 450062, Russian Federation), E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Borodin A.V., Gazprom Neft (Pochtamptskaya, 3-5, Sankt-Geterburg, 190000, Rusian Federation)
Kolchina G.Yu., Sterlitamak branch of the Bashkir State University, (47a Lenina str., Sterlitamak, 453103, Russian Federation)
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ABSTRACT
Shows the composition of oil Fishery-gas, investigated major fraction thereof. The paper presents possible ways of utilization of associated oil Fishery-gas. The basic technological processes for the extraction of oil Fishery-gas heavy hydrocarbons, as well as the concepts of gas processing plants.
Keywords: oil Fishery-gas, dry stripped gas, broad fraction of light hydrocarbons, stable natural gasoline, synthesis-gas.
Value accounting associated petroleum gas at structuring and resource calculation
L.G. Tkachenko,
L.V. Saprykina, NIPIgaspererabotka (118, st. Krasnaya, Krasnodar, 350000, Russian Federation)
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ABSTRACT
The problem of the most accurate of associated petroleum gas (APG), excluding its oilfield. From properly organized accounting associated gas depends very much, for example: inventory forecasting APG and development prospects, the choice of destinations using APG technology and selection of optimal processing capacity of APG. Proposed for tackling these problems.
Keywords: petroleum gas, metering devices, recycling, business accounting APG.
Shale gas — natural gas produced from oil shale deposit
Guseynov F.I., prof., Zelinsky Institute of Organic Chemistry RAS (47, Leninsky Prospect, Moscow, 119991, Russian Federation) E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
Telyashev R.G., General Director, LUKOIL-Nizhegorodniinefteproekt(147A, st. M.Gorky, Nizhny Novgorod, 603950, Russian Federation)
Obryvalina A.N., LUKOIL-Nizhegorodniinefteproekt(147A, st. M.Gorky, Nizhny Novgorod, 603950, Russian Federation)
Kustov L.M., prof., Zelinsky Institute of Organic Chemistry RAS (47, Leninsky Prospect, Moscow, 119991, Russian Federation)
ABSTRACT
The prospects for market development of shale gas on the basis of features of the technology of natural gas in shale deposits and analysis of volumes of its global reserves. The stages of shale gas production: hydraulic fracturing, pipeline and drill site, drilling, well casing, perforating, drilling, reservoir, production, isolation and redemption well. Presented the technological features of horizontal drilling through shale.
On the basis of world agencies production volumes and volumes of proved reserves of shale gas in the countries of the world are the prospects for shale gas production.
Keywords: shale gas extraction technology, hydraulic fracturing, horizontal drilling, global stocks and prospects for development.
CHEMISTRY AND TECHNOLOGY
Preparation of adducts transfer metal oil porphyrine complexes with molecular oxygen
Agahuseynova M.M.,
Abdullayeva G.N.
Azerbaijan State Oil Academiy (Azadliq avenue-20, Baku, Azrebaidjan)
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ABSTRACT
It has been prepared oil porphyrine concentrate by extraction of heavy oils and asphaltenes with acetone and ethanol. As result of metallation reaction of porphyrine concentrate with phenylsodium it has been prepared disodium substituted derivatives, which by interaction with transfer metal salts gives transfer metalporphyrine complexes. The structure of synthesized porphyrine complexes has been studies using infra-red-and electron spectroscopy methods.
It have been determined catalytic activities of these complexes.
It is necessary to mark that synthesized transfer metalporphyrine complexes gives adducts with molecular oxygen.
Transfer metalporphyrine-molecular oxygen complexes oxidize unsaturated organic compounds and alkenes. It has been shown that molecular oxygen- transfer metal-porphyrine adducts oxidize alkenes giving corresponding oxiranes.
Keywords: oil metalloporphyrins, oxygenation reaction, catalytic activity.
Initiation of conversion bioethanol hydrogen peroxide
Tretyakov V.F., Lomonosov Moscow State University of Fine Chemical Technology (86, prosp.Vernadskogo, Moscow, 119571, Russuan Federation)
Than Thi Quynh Nhu, Lomonosov Moscow State University of Fine Chemical Technology (86, prosp.Vernadskogo, Moscow, 119571, Russuan Federation)
Talyshinskiy R.M., Topchiev Institute of Petrochemical Synthesis, RAS (29, Leninsky prosp., Moscow, 119991, Russuan Federation)
Ilolov A.M., Topchiev Institute of Petrochemical Synthesis, RAS(29, Leninsky prosp., Moscow, 119991, Russuan Federation)
Frantsuzova N.A., Lomonosov Moscow State University of Fine Chemical Technology (86, prosp.Vernadskogo, Moscow, 119571, Russuan Federation)
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ABSTRACT
A new catalytic process initiated biofuels and important petrochemical products from ethanol. Investigated the effect of initiating the process of hydrogen peroxide in ethanol, catalytically converting aromatic hydrocarbons. It is shown that the overall yield of aromatics increases with contact time and temperature conditions, in the absence of hydrogen peroxide is rapid coking of the catalyst surface of zeolite HZSM-5. Hypothesized modifying action of hydrogen peroxide by hydroxylation of the catalyst surface and the initiation of the limiting step of ethylene oligomerization with peroxide radicals HO2•.
Keywords: ethanol, hydrogen peroxide, aromatic hydrocarbons, ethylene, gasoline, ecology, zeolite HZSM-5, initiation, catalysis, oligomerization, hydroxylation peroxidic radicals.
Conducting pilot testing of sorbents in the factory
Adzhiev A.Yu., NIPIgazpererabotka (118, st. Krasnaya, Krasnodar, 350000, Russian Federation)
Moreva N.P., NIPIgazpererabotka (118, st. Krasnaya, Krasnodar, 350000, Russian Federation)
Dolinskaya N.I., NIPIgazpererabotka (118, st. Krasnaya, Krasnodar, 350000, Russian Federation)
Tchernoskutov A.P., NIPIgazpererabotka (118, st. Krasnaya, Krasnodar, 350000, Russian Federation)
Khramtsov V.I., SiburTyumenGaz (10, st. Omskaya, Nizhnevartovsk, Tyumen region, Khanty-Mansi Autonomous district, 628616, Russian Federation)
Ivanov S.A., SiburTyumenGaz (10, st. Omskaya, Nizhnevartovsk, Tyumen region, Khanty-Mansi Autonomous district, 628616, Russian Federation)
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ABSTRACT
«NIPIgazpererabotka» long been the processes of adsorption drying, which allowed summarize lessons learned and highlight a few important criteria to determine the optimal operating conditions of zeolites for plants adsorption drying APG and, as a consequence, their service life. The article presents the experience of monitoring of the operational characteristics of zeolites. Monitoring constant monitoring, the identification and selection of the most qualitative zeolites from different manufacturers, both domestic and foreign, that enable to extend service life of the sorbent plants adsorption drying it is desirable to four years, which will significantly reduce the operating costs for the purchase and restart zeolites.
In the article in detail by the stage testing on a real gas samples zeolites type KA and their comparison, which were carried out on pilot plant of gas drying, allowing to conduct research sorbents in a large range of pressure, temperature and velocity of the gas stream. It is concluded that the domestic sorbent KA is not inferior to the foreign one, and the operating capacity surpasses it.
Keywords: gas dehydration unit, sorbent, zeolite, pilot installation, sorbent KA.
EQUIPMENTS
Laboratory installation hydrotreating is a tool for optimization of production of fuels with ultra low sulfur
Stratiev D.S., LUKOIL Neftochim Burgas (Burgas, Bulgaria)
Shishkov I.K., LUKOIL Neftochim Burgas (Burgas, Bulgaria)
Bonchev I.R., LUKOIL Neftochim Burgas (Burgas, Bulgaria)
Obryvalina A.N., LUKOIL–Nizhegorodniinefteproekt (st. Gorky, 147A, Nizhny Novgorod, 603950, Russian Federation)
Telyashev R.G., LUKOIL–Nizhegorodniinefteproekt (st. Gorky, 147A, Nizhny Novgorod, 603950, Russian Federation)
E-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.
ABSTRACT
Provides an overview of the possibilities of laboratory facilities hydrotreating and their application for cost effective production of automotive fuels ultra low sulfur at the refinery. Considers the types of laboratory facilities for testing process hydrodesulfurization oil fractions. Progress in experimental facilities for laboratory research processes hydrodesulfurization oil fractions enables to reach perfect correlation between the results obtained in industrial and laboratory units under other equal conditions.
Results of laboratory research process hydrodesulfurization distillate fractions and choice of suitable catalytic systems for industrial hydrodesulfurization units at the plant «LUKOIL Neftochim Burgas», which allowed to save the order of several million dollars.
Keywords: diesel fuel, ultra low sulfur diesel, production optimization, laboratory setting of hydrotreating.
PORTRET COMPANIES
The institute for Research and Planning of Gas Refining Industry (NIPIGASPERERABOTKA). An introduction
Breschenko E.M.,
Kapralov V.P.
Veterans of «NIPIgaspererabotka» (118, st. Krasnaya, Krasnodar, 350000, Russian Federation)
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Presents the stages of the historical development of the «NIPIgaspererabotka» (NIPIGAS) — Russian research and design center in the field of gathering, treatment, transportation and processing of gas.
ANNIVERSARIESTS
Department of Technology of Petrochemical Synthesis and Artificial Fuel of Lomonosov Moscow State University of Fine Chemical Technologies
EXHIBITIONS. CONFERENCES
Results of the Forum «Plastics of Russia 2013»
CIS Petrochemicals Conference
LIST OF ARTICLES PUBLISHED IN 2013
