CONTENTS of journal "OIL & GAS CHEMISTRY" 4·2018 (Russia)


ENERGY SAVING, NEW AND RENEWABLE SOURCES OF ENERGY

LOW-EMISSION EFFICIENT INFRARED BURNER FOR COOKING APPLICATIONS (P. 5-9)
Dmitrii A. Lyalin, Nikolai Ya. Vasilik, Aleksandr A. Zaharov, Vladimir S. Arutyunov, Vladimir M. Shmelev
Semenov Institute of Chemical Physics, Russian Academy of  Sciences, 119991, Moscow, Russia
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ORCID http://orcid.org/0000-0003-1491-894X,
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ORCID https://orcid.org/0000-0002-0836-2431,
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ORCID http://orcid.org/0000-0003-0339-0297,
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ORCID https://orcid.org/0000-0002-4848-7423,
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ABSTRACT
Environmental protection and fire safety of domestic devices are the most important features for customer who is situated close to gas cooker. In this paper the cooking application of infrared burners fueled by low pressure natural gas is considered. The efficient work of devices which satisfied the strictest demands for NOx and CO emission is demonstrated. Based on experimental comparison of different burner design, the burner with low-pressure air blower was chosen as more perspective one in this field of application.
KEYWORDS: infrared burner, gas cooker.
For citation: Lyalin D.A., Vasilik N.Ya., Zaharov A.A., Arutyunov V.S., Shmelev V.M. LOW-EMISSION EFFICIENT INFRARED BURNER FOR COOKING APPLICATIONS. Oil & Gas Chemistry. 2018, no. 4, pp. 5 - 9 .
DOI:10.24411/2310-8266-2018-10401.
Acknowledgments: This work was performed within the framework of the Programs of Fundamental Research of the Russian Academy of Sciences for 2013−2020 on the research issue of IChP RAS No. 44.8 (Theme number in Federal Agency for Scientific Organizations: 0082-2014-0012. State registration number of Center of Information Technologies and Systems for Executive Power Authorities (CITIS): AAAA-A17-117040610346-5).

CHEMICAL TECHNOLOGIES AND PRODUCTS

CHARACTERISTICS OF QUANTUM CHEMICAL PROGRAMS, FOR THE CALCULATION OF MOLECULES, MOLECULAR SYSTEMS AND SOLID BODIES (P. 10-16)
Galina Yu. Kolchina1, Ilnur I. Khasanov2, Elena A. Loginova2, Olga Yu. Poletaeva2, A… Yu. Bakhtina2
1Sterlitamak branch of the Bashkir State University,
453103, Sterlitamak, Russia
ORCID: http://orcid.org/0000-0003-2808-4827, E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
2Ufa State Petroleum Technological University,
450062, Ufa, Russia
ORCID: http://orcid.org/0000-0002-3422-1237 , E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ORCID: http://orcid.org/0000-0002-9602-0051 , E-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
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ABSTRACT
This article describes the main points of the development of computer chemistry, analyzes the main approaches to solving problems and presents the main calculation methods in the field of quantum chemistry. Frequently used quantum-chemical programs for calculating the parameters of molecules and molecular systems are also considered, their brief description is given.
KEYWORDS: quantum chemistry, Schrödinger equation, programs, semi-empirical and nonempirical methods, hybrid density functional method, molecular reactivity.
For citation: Kolchina G.Yu., Khasanov I.I., Loginova E.A., Poletaeva O.Yu., Bakhtina A.Yu. CHARACTERISTICS OF QUANTUM CHEMICAL PROGRAMS, FOR THE CALCULATION OF MOLECULES, MOLECULAR SYSTEMS AND SOLID BODIES. Oil & Gas Chemistry. 2018, no. 4, pp. 10 - 16. DOI:10.24411/2310-8266-2018-10402

CONTEMPORARY STATE AND PROSPECTS OF DEVELOPMENT OF AMMONIA PRODUCTION IN RUSSIA (P. 17-21)
Michael Kh. Sosna, Maria A. Goldobina
Gubkin Russian State University of Oil and Gas, 119991, Moscow, Russia
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ABSTRACT
The article presents a chronology of the ammonia production development in Russia, the main technological solutions that affect the energy performance of the process. An assessment of the current state of the industrial capacity of ammonia synthesis is given. The projects of 2018 and the technologies implemented in them are considered, which will make it possible to obtain a significant increase in ammonia production in Russia. In addition, recommendationson a further possible way of improving the process energy were given.
KEYWORDS: ammonia, ammonia production, ammonia synthesis, synthesis gas, natural gas conversion.
For citation: Sosna M.Kh., Goldobina M.A. CONTEMPORARY STATE AND PROSPECTS OF DEVELOPMENT OF AMMONIA PRODUCTION IN RUSSIA. Oil & Gas Chemistry. 2018, no. 4, pp. 17 - 21.
DOI:10.24411/2310-8266-2018-10403

STUDY OF THE MEDICINAL OIL ECOSYSTEM OF THE NAFTALAN FIELD, AS THE HABITAT OF MICROORGANISMS (P. 22-26)
Ajdar G. Talybly1, Vafa A. Adigozalova2
1Institute of Microbiology, National Academy of Sciences of Azerbaijan, AZ1073, Baku, Azerbaijan
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2Azerbaijan State Academy of Physical Culture and Sport, AZ1072, Baku, Azerbaijan
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ABSTRACT
It was found that the horizons of the Naftalan field with medicinal oil are characterized by a low bacterial population. The reason for this is assumed to be the complex composition of hydrocarbons that are difficult to be involved in the exchange of most microorganisms, as well as the reaction of the pH of produced water. It has been shown that representatives of hydrocarbon-oxidizing bacteria of the genera: Pseudomonas, Bacillus and Rhodococcus are widely used in the horizons with therapeutic oil. It is proved that in the therapeutic properties of naphthalan oil the main role belongs to the bacteria of the genus Bacillus subtilis and Rhodococcus sp. It indicates the possibility of using these microorganisms in order to restore the biological activity of spent medicinal oil, as well as for the conversion into therapeutic, light industrial oil from the deeper horizons of the Naftalan field.
KEYWORDS: therapeutic oil, Naftalan field, hydrocarbon-oxidizing microorganisms.
For citation: Talybly A.G., Adigozalova V.A. Study of the medicinal oil ecosystem of the Naftalan field, as the habitat of microorganisms. Oil & Gas Chemistry. 2018, no. 4, pp. 22-26.
DOI:10.24411/2310-8266-2018-10404

PETROLEUM COMPLEXES OF METALPORPHYRINS AND THEIR DIOХYGEN ADDUCTS (P. 27-29)
Minira M. Agaguseynova, G… I. Imanova
Azerbaijan State University of Oil and Industry
AZ1010, Baku, Azerbaijan
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ABSTRACT
The formation of dioxygen adducts of petroleum derived metalporphyrins in the receptor cavity has been investigated. It is established that the oxidation reaction proceeds selectively and with a high yield, and the clathrate compound is created due to non-valence bonds. The chemical equilibrium constants of the oxidation reaction were calculated and it was found that the chemical equilibrium constants with the participation of receptors are 4–5 orders of magnitude higher than the chemical equilibrium constants of the oxidation reaction of metalloporphyrins without receptors. In all metal porphyrin complexes, a pattern has been established in the formation of the peroxide structure of dioxygen adducts, which is confirmed by the presence in the IR spectra of specific absorption bands of 1135–1140 cm – 1, characteristic of the О2-2 fragment.
KEYWORDS: receptor, metalloporphyrins, dioxygen adducts, dextrins, oxygen.
For citation: Agaguseynova M.M., Imanova G.I. PETROLEUM COMPLEXES OF METALPORPHYRINS AND THEIR DIOХYGEN ADDUCTS. Oil & Gas Chemistry. 2018, no. 4, pp. 27-29.
DOI:10.24411/2310-8266-2018-10405

KINETICS AND CATALYSIS

INTERACTION OF PHENOL WITH ETHYL ETHERS CYCLOHEXEN AND 4-METHYL-CYCLOHEXENE OF CARBONIC ACID IN THE PRESENCE OF KU-23 CATALYST (P. 30-33)
Mehriban V. Nagiyeva, Chingiz K. Rasulov, Zaur Z. Agamaliev, Irada I. Alekperova
Yu.H. Mamedaliyev's Institute of Petrochemical Processes of the National Academy of Sciences of Azerbaijan, AZ1025, Baku, Azerbaijan
ORCID: https://orcid.org/0000-0001-7823-0832,  Е-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ORCID: https://orcid.org/0000-0003-4999-2955,  Е-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ORCID: https://orcid.org/0000-0003-2866-1401,
Е-mail: zaur_agamaliyev@hotmail.cоm
ORCID: https://orcid.org/0000-0003-1694-4914, Е-mail: Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
The reactions of cycloalkylation of phenol with ethyl esters of cyclohexene and 4-methylcyclohexenecarboxylic acid in the presence of catalyst KU-23. It was found that at a temperature of 110-120 ° C, a reaction time of 4-5 hours, a molar ratio of phenol to ether of 1: 1 mol / mol and a catalyst amount of 7-10%, the yield of 4- (4-hydroxyphenyl) -cyclohexane acid and ethyl ester of the 4- (4-hydroxyphenyl) -4'-methylcyclohexane carboxylic acid are 72.4 and 76.5%, respectively, from the theory to the phenol taken, and the selectivity is 92.7 and 94.4% by the target product.
KEYWORDS: phenol, ethyl esters of cyclohexanecarboxylic acid, cycloalkylation.
For citation: Nagiyeva M.V., Rasulov Ch.K., Agamaliev Z.Z., Alekperova I.I. INTERACTION OF PHENOL WITH ETHYL ETHERS CYCLOHEXEN AND 4-METHYL-CYCLOHEXENE OF CARBONIC ACID IN THE PRESENCE OF KU-23 CATALYST. Oil & Gas Chemistry. 2018, no. 4, pp. 30-33.
DOI:10.24411/2310-8266-2018-10406

DEVELOPMENT OF THE FUNDAMENTAL PRINCIPLES OF INITIATED HETEROGENEOUS CATALYSIS (P. 34-38)
Anton L. Maksimov, Valentin F. Tretyakov, Rashid M. Talyshinsky
A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of  Sciences, 119991, Moscow, Russia
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ABSTRACT
On the basis of generalization of works in the field of the initiated heterogeneous catalysis the phenomenology of catalysis with definition of the catalytic system including the catalyst, the initiator and the reaction medium develops. The presence of the initiator in the system explains the synergetic phenomena based on the simultaneous acceleration of achieving equilibrium by the catalyst and performing the work of the catalytic system as a whole. The mechanism of the functional action of hydrogen peroxide used as the initiator of the catalytic conversion of lower alcohols is analyzed.
KEYWORDS: catalytic system, catalyst, initiator, reaction medium, hydrogen peroxide, mechanism.
For citation: Maksimov A.L., Tretyakov V.F., Talyshinsky R.M. DEVELOPMENT OF THE FUNDAMENTAL PRINCIPLES OF INITIATED HETEROGENEOUS CATALYSIS. Oil & Gas Chemistry. 2018, no. 4, pp.  34-38.  
DOI:10.24411/2310-8266-2018-10406.

NOBEL LAUREATES

Nobel prize in chemistry – 2017: a new look at biomolecules (P. 39-42)

THE LIST OF ARTICLES PUBLISHED IN THE JOURNAL “OIL & GAS CYTMISTRY” IN 2018 (P. 43-44)

 

 

Фотогалерея

КОНТАКТЫ


Индекс: 119313
Москва, улица Гарибальди, д. 4Г
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